Methyl 2-oxocyclohex-3-ene-1-carboxylate

Base Information

• Chemical Name: Methyl 2-oxocyclohex-3-ene-1-carboxylate
• CAS No.: 127943-91-3
• Molecular Formula: C8H10O3
• Molecular Weight: 154.166
• DSSTox Substance ID: DTXSID10525557
• Nikkaji Number: J3.328.012B
• Mol file: 127943-91-3.mol

Synonyms:127943-91-3;Methyl 2-oxocyclohex-3-ene-1-carboxylate;3-Cyclohexene-1-carboxylic acid, 2-oxo-, methyl ester;DTXSID10525557;methyl 2-oxo-3-cyclohexene-1-carboxylate;2-oxo-cyclohex-3-ene-1-carboxylic acid methyl ester

Chemical Property of Methyl 2-oxocyclohex-3-ene-1-carboxylate

Chemical Property:

• XLogP3: 1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 154.062994177
• Heavy Atom Count: 11
• Complexity: 205

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(=O)C1CCC=CC1=O

Technology Process of Methyl 2-oxocyclohex-3-ene-1-carboxylate

There total 7 articles about Methyl 2-oxocyclohex-3-ene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

cyclohexenone (930-68-7) + methyl cyanoformate (17640-15-2) → methyl 2-oxocyclohex-3-ene-1-carboxylate (127943-91-3)

Guidance literature:

cyclohexenone; With ammonia; lithium; In diethyl ether; tert-butyl alcohol; at -78 ℃; for 0.25h; Inert atmosphere;

methyl cyanoformate; In diethyl ether; at -78 - 0 ℃; for 0.75h; regiospecific reaction; Inert atmosphere;

DOI:10.15227/orgsyn.070.0256

Reference yield: 76.0%

2-Ethoxy-3,4-dihydro-6-methyl-2H-pyran-5-carbonsaeure-methylester (99789-32-9) → methyl 2-oxocyclohex-3-ene-1-carboxylate (127943-91-3)

Guidance literature:

With poly(divinylbenzene-co-4-vinylbenzenesulfonic acid); poly(divinylbenzene-co-4-vinylbenzyl amine); In nitromethane; water; at 100 ℃; for 8h;

DOI:10.1039/d0nj01357a

Reference yield: 60.0%

methyl 2-butoxy-6-methyl-3,4-dihydro-2H-pyran-5-carboxylate (1266617-35-9) → methyl 2-oxocyclohex-3-ene-1-carboxylate (127943-91-3)

Guidance literature:

With hyper-cross-linked polymer nanospheres with acid and base sites; In nitromethane; water; at 100 ℃; for 4h;

DOI:10.1021/acscatal.6b03631

upstream raw materials:

cyclohexenone

methyl cyanoformate

nitromethane

p-toluidine

Downstream raw materials:

C₁₇H₂₀O₆

C₁₅H₁₆O₄

C₁₄H₁₄O₃

C₂₁H₂₃NO₅

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 127943-91-3 3-Cyclohexene-1-carboxylic acid, 2-oxo-, methyl ester

Send

Send

Metric Ton KG G Pound L ML

Send

Send