[1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)-κ2P,P'](η6-chlorobenzene)hydridoruthenium(II) trifluoromethanesulfonate

Base Information

• Chemical Name: [1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)-κ2P,P'](η6-chlorobenzene)hydridoruthenium(II) trifluoromethanesulfonate
• CAS No.: 528572-45-4
• Molecular Formula: CF₃O₃S*C₅₀H₃₈ClP₂Ru
• Molecular Weight: 986.393
• Mol file: 528572-45-4.mol

Synonyms:

Chemical Property of [1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)-κ2P,P'](η6-chlorobenzene)hydridoruthenium(II) trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)-κ2P,P'](η6-chlorobenzene)hydridoruthenium(II) trifluoromethanesulfonate

There total 1 articles about [1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)-κ2P,P'](η6-chlorobenzene)hydridoruthenium(II) trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

Ru(OCOCH3)2{(S)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl)} (114818-52-9,104713-03-3,261948-85-0,325146-81-4,104621-48-9) + trifluorormethanesulfonic acid (1493-13-6) + chlorobenzene (108-90-7) → [1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)-κ2P,P'](η6-chlorobenzene)hydridoruthenium(II) trifluoromethanesulfonate (528572-45-4)

Guidance literature:

In isopropyl alcohol; heating a suspn. of Ru complex and arene in isopropanol to 75°C, treating with CF3SO3H; cooling to room temp., concg. in vac., pptn. by addn. of pentane, filtration, washing with diethyl ether, drying; elem. anal.;

DOI:10.1002/1522-2675(200211)85:11<3937::AID-HLCA3937>3.0.CO;2-X

upstream raw materials:

Ru(OCOCH₃)2{(S)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl)}

trifluorormethanesulfonic acid

chlorobenzene