cis,trans,cis-ethane-1,2-diaminebis(hydroxo)bis(pentafluorophenyl)platinum(IV)

Base Information

• Chemical Name: cis,trans,cis-ethane-1,2-diaminebis(hydroxo)bis(pentafluorophenyl)platinum(IV)
• CAS No.: 166669-30-3
• Molecular Formula: C₁₄H₁₀F₁₀N₂O₂Pt
• Molecular Weight: 623.31
• Mol file: 166669-30-3.mol

Synonyms:

Chemical Property of cis,trans,cis-ethane-1,2-diaminebis(hydroxo)bis(pentafluorophenyl)platinum(IV)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis,trans,cis-ethane-1,2-diaminebis(hydroxo)bis(pentafluorophenyl)platinum(IV)

There total 1 articles about cis,trans,cis-ethane-1,2-diaminebis(hydroxo)bis(pentafluorophenyl)platinum(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

ethane-1,2-diaminebis(pentafluorophenyl)platinum(II) + dihydrogen peroxide (7722-84-1) → cis,trans,cis-ethane-1,2-diaminebis(hydroxo)bis(pentafluorophenyl)platinum(IV) (166669-30-3)

Guidance literature:

In acetone; excess 30% aq. H2O2, refluxing for 1 h; solvent removal (vac.), washing (cold Me2CO); elem. anal.;

DOI:10.1016/0022-328X(94)05329-A

Reference yield: 75.0%

butanoic acid anhydride (106-31-0) + cis,trans,cis-ethane-1,2-diaminebis(hydroxo)bis(pentafluorophenyl)platinum(IV) (166669-30-3) → trans,cis,cis,trans-bis(butanoato)ethane-1,2-diaminebis(pentafluorophenyl)platinum(IV) (166669-34-7)

Guidance literature:

In diethyl ether; byproducts: PrCO2H; excess anhydride, stirring at room temp. for 60 h; solvent removal (vac.), dissoln. in Me2CO, water addn., cooling (pptn.),collection (filtration), drying in air; elem. anal.;

DOI:10.1016/0022-328X(94)05329-A

upstream raw materials:

dihydrogen peroxide

Downstream raw materials:

trans,cis,cis,trans-bis(butanoato)ethane-1,2-diaminebis(pentafluorophenyl)platinum(IV)