dichloroethylene bis(phenyl sulfide) palladium (II)

Base Information

• Chemical Name: dichloroethylene bis(phenyl sulfide) palladium (II)
• CAS No.: 21215-89-4
• Molecular Formula: C₁₄H₁₄Cl₂PdS₂
• Molecular Weight: 423.723
• Mol file: 21215-89-4.mol

Synonyms:

Chemical Property of dichloroethylene bis(phenyl sulfide) palladium (II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloroethylene bis(phenyl sulfide) palladium (II)

There total 3 articles about dichloroethylene bis(phenyl sulfide) palladium (II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

sodium tetrachloropalladate(II) + 1,2-bis(phenylthio)ethane (622-20-8) → dichloroethylene bis(phenyl sulfide) palladium (II) (859186-05-3,21215-89-4)

Guidance literature:

In water; acetone; for 12h;

DOI:10.1039/c4dt03471f

Reference yield: 74.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + 1,2-bis(phenylthio)ethane (622-20-8) → dichloroethylene bis(phenyl sulfide) palladium (II) (859186-05-3,21215-89-4)

Guidance literature:

In acetone; N2-atmosphere; slow addn. of Pd-complex to soln. of dithioether, stirring (20 min, pptn.); filtration, washing (acetone), drying (vac.); elem. anal.;

DOI:10.1016/S0020-1693(00)88892-1

Reference yield:

thiophenol (108-98-5) → dichloroethylene bis(phenyl sulfide) palladium (II) (859186-05-3,21215-89-4)

Guidance literature:

Multi-step reaction with 3 steps

1: sodium hydroxide / water; ethanol / 1 h / Reflux

2: water; ethanol / 5 h / Reflux

3: water; acetone / 12 h

With sodium hydroxide; In ethanol; water; acetone;

DOI:10.1039/c4dt03471f

upstream raw materials:

1,2-bis(phenylthio)ethane

bis(benzonitrile)palladium(II) dichloride

thiophenol

Downstream raw materials:

bis(ethylenediamine)palladium(II) chloride