BIS(ETHYLENEDIAMINE)PALLADIUM(II) DICHLORIDE

Base Information

• Chemical Name: BIS(ETHYLENEDIAMINE)PALLADIUM(II) DICHLORIDE
• CAS No.: 16483-18-4
• Molecular Formula: C₄H₁₆N₄Pd*2Cl
• Molecular Weight: 297.524
• Mol file: 16483-18-4.mol

Synonyms:Bis(ethylenediamine)palladiumdichloride (7CI); Palladium(2+), bis(1,2-ethanediamine-N,N')-, dichloride,(SP-4-1)-; Palladium(2+), bis(1,2-ethanediamine-kN,kN')-, dichloride, (SP-4-1)- (9CI); Palladium(2+), bis(ethylenediamine)-,dichloride (8CI); Bis(ethylenediamine)palladium(2+) dichloride

Chemical Property of BIS(ETHYLENEDIAMINE)PALLADIUM(II) DICHLORIDE

Chemical Property:

• Boiling Point: 119.7°Cat760mmHg
• Flash Point: 33.9°C
• PSA: 104.08000
• Density: g/cm³
• LogP: -5.38320

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bis(ethylenediamine)palladium(II) Dichloride >98.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BIS(ETHYLENEDIAMINE)PALLADIUM(II) DICHLORIDE

There total 19 articles about BIS(ETHYLENEDIAMINE)PALLADIUM(II) DICHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

dichloro[2-(1'-pyrazolyl)pyridine-N,N']palladium (370590-60-6) + ethylenediamine (107-15-3,85404-18-8) → bis(ethylenediamine)palladium(II) chloride (16483-18-4)

Guidance literature:

In methanol; water; mixt. of ligand in MeOH and Pd complex in MeOH-H2O heated; ether added;

DOI:10.1139/v05-110

Reference yield:

ethylenediamine (107-15-3,85404-18-8) + palladium dichloride → bis(ethylenediamine)palladium(II) chloride (16483-18-4)

Guidance literature:

In methanol; pptn.; filtration, washing (methanol), drying (vac.); elem. anal.;

Reference yield:

[palladium(II)dichloride(1,10-phenanthroline)] (14783-10-9) → bis(ethylenediamine)palladium(II) chloride (16483-18-4)

Guidance literature:

With ethylenediamine; In methanol; N,N-dimethyl-formamide; 25 °C, DMF:MeOH (1:1), 10-fold excess of nucleophile; monitored spectrophotometrically or conductometrically; Kinetics;

DOI:10.1039/DT9820002445

upstream raw materials:

cis-dichloro(ethylenediamine)palladium(II)

diamminedichloropalladium(II)

ethylenediamine

[palladium(II)dichloride(1,10-phenanthroline)]

Downstream raw materials:

cis-dichloro(ethylenediamine)palladium(II)

Refernces

• 1、 Asakura, Hiroyuki,Chang, Albert,Chen, Benjamin W. J.,Hülsey, Max J.,He, Qian,Sun, Qiming,Tanaka, Tsunehiro,Wang, Chi-Hwa,Wang, Ning,Yan, Ning,Yang, Chia-Min,Yu, Jihong. "Zeolite-Encaged Pd–Mn Nanocatalysts for CO2 Hydrogenation and Formic Acid Dehydrogenation". . p. 20183 - 20191. Retrieved 2020.
• 2、 Sharma, Kripa,Fahmi, Nighat,Singh. "Synthesis and structural elucidation of heterobimetallic complexes comprising palladium(II) and a group fourteen element". . p. 1291 - 1293. Retrieved 2007/10/03.