[RuHCl(CO)(triphenylphosphine)2(triisopropyl phosphite)]

Base Information

• Chemical Name: [RuHCl(CO)(triphenylphosphine)2(triisopropyl phosphite)]
• CAS No.: 162855-95-0
• Molecular Formula: C₄₆H₅₂ClO₄P₃Ru
• Molecular Weight: 898.361
• Mol file: 162855-95-0.mol

Synonyms:

Chemical Property of [RuHCl(CO)(triphenylphosphine)2(triisopropyl phosphite)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [RuHCl(CO)(triphenylphosphine)2(triisopropyl phosphite)]

There total 1 articles about [RuHCl(CO)(triphenylphosphine)2(triisopropyl phosphite)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) + triisopropyl phosphite (116-17-6) → [RuHCl(CO)(triphenylphosphine)2(triisopropyl phosphite)] (162855-95-0)

Guidance literature:

In toluene; byproducts: PPh3; N2-atmosphere; slight excess of Ru-complex, stirring for 0.5 h; evapn., washing (hexane), drying (vac.); elem. anal.;

DOI:10.1016/0022-328X(94)05181-A

Reference yield: 56.0%

bis(triphenylphosphine)-rhenium heptahydride (12103-40-1) + [RuHCl(CO)(triphenylphosphine)2(triisopropyl phosphite)] (162855-95-0) → [(CO)(PPh3)2Re(μ-H)3Ru(P(C6H5)3)2(P(O(i)Pr)3)]

Guidance literature:

With KH; In tetrahydrofuran; byproducts: H2, Cl(1-); N2-atmosphere; stirring Re-complex with excess KH for 1 h, filtration, addn. to equimolar amt. of Ru-complex, stirring (60°C, 2 h); evapn., dissoln. in PhMe, chromy. (Al2O3, Et2O/THF=1:1), evapn. (vac.),recrystn. (PhMe/hexane, 0°C); elem. anal.;

DOI:10.1016/0022-328X(94)05181-A

upstream raw materials:

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

triisopropyl phosphite