C₁₆H₃₀O₅S

Base Information

• Chemical Name: C₁₆H₃₀O₅S
• CAS No.: 1454891-14-5
• Molecular Formula: C₁₆H₃₀O₅S
• Molecular Weight: 334.477
• Mol file: 1454891-14-5.mol

Synonyms:

Chemical Property of C₁₆H₃₀O₅S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₆H₃₀O₅S

There total 3 articles about C₁₆H₃₀O₅S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-[(1S)-1,5-dimethylhex-4-enyl]cyclohex-2-en-1-one (343239-55-4) → C16H30O5S (1454891-14-5)

Guidance literature:

Multi-step reaction with 3 steps

1: chloro(1,5-cyclooctadiene)rhodium(I) dimer; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl / tetrahydrofuran; n-heptane / 24 h / -5 - 2 °C / Inert atmosphere

2: methanesulfonamide; AD-mix-β / tert-butyl alcohol; water / 24 h / 0 - 2 °C

3: pyridine / 1 h / 0 - 20 °C

With pyridine; chloro(1,5-cyclooctadiene)rhodium(I) dimer; methanesulfonamide; AD-mix-β; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl; In tetrahydrofuran; n-heptane; water; tert-butyl alcohol; 2: |Sharpless Dihydroxylation;

DOI:10.1021/np5003753

Reference yield:

(1R,4R)-1-methyl-4-[(S)-6-methylhept-5-en-2-yl]cyclohex-2-enol (87680-38-4) → C16H30O5S (1454891-14-5)

Guidance literature:

Multi-step reaction with 2 steps

1: methanesulfonamide; AD-mix-β / tert-butyl alcohol; water / 24 h / 0 - 2 °C

2: pyridine / 1 h / 0 - 20 °C

With pyridine; methanesulfonamide; AD-mix-β; In water; tert-butyl alcohol; 1: |Sharpless Dihydroxylation;

DOI:10.1021/np5003753

Reference yield:

(3R,6R,7S,10R)-1-bisabolen-3,10,11-triol (1443410-91-0) + methanesulfonyl chloride (124-63-0) → C16H30O5S (1454891-14-5)

Guidance literature:

With pyridine; at 0 - 20 ℃; for 1h; regioselective reaction;

DOI:10.1021/np5003753

upstream raw materials:

(3R,6R,7S,10R)-1-bisabolen-3,10,11-triol

methanesulfonyl chloride

4-[(1S)-1,5-dimethylhex-4-enyl]cyclohex-2-en-1-one

(1R,4R)-1-methyl-4-[(S)-6-methylhept-5-en-2-yl]cyclohex-2-enol

Downstream raw materials:

(3R,6R,7S,10S)-10,11-epoxy-1-bisabolen-3-ol