cis-[PtMePh(PMePh₂)2]

Base Information

• Chemical Name: cis-[PtMePh(PMePh₂)2]
• CAS No.: 75095-27-1
• Molecular Formula: C₃₃H₃₄P₂Pt
• Molecular Weight: 687.66
• Mol file: 75095-27-1.mol

Synonyms:

Chemical Property of cis-[PtMePh(PMePh₂)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[PtMePh(PMePh₂)2]

There total 1 articles about cis-[PtMePh(PMePh₂)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-Pt(phenyl)F(P(C6H5)2CH3)2 + trimethyl(phenyl)stannane (934-56-5) → cis-[PtPh2(PMePh2)2] (51538-76-2) + trans-Pt(phenyl)(methyl)(P(C6H5)2CH3)2 (75095-27-1) + trans-Pt(phenyl)2(P(C6H5)2CH3)2 (51538-76-2,51538-77-3)

Guidance literature:

In dichloromethane-d2; N2; loading NMR tube with Pt complex and dichloromethane-d2, adding excess tin compd. to thermostated mixt., allowing to stay for 18 h at room temp.; not isolated, detected by NMR;

DOI:10.1021/om030524i

Reference yield:

cis-[PtMePh(PMePh2)2] (75095-27-1) → cis-[PtClPh(PMePh2)2] (79767-75-2)

Guidance literature:

With hydrogenchloride; In diethyl ether; byproducts: CH4; a solution of HCl in ether was added to the Pt complex solution in ether, cooled to -78°C, allowed to warm to room temp., methane was evolved, reaction time less then 5 min; evapn. of the solvent;

DOI:10.1021/ic00131a061

upstream raw materials:

trimethyl(phenyl)stannane

Downstream raw materials:

cis-[PtClPh(PMePh₂)2]