[Ir((CH₃)3CS)(CO)(P(C₆H₅)3)]2

Base Information

• Chemical Name: [Ir((CH₃)3CS)(CO)(P(C₆H₅)3)]2
• CAS No.: 63264-36-8
• Molecular Formula: C₄₆H₄₈Ir₂O₂P₂S₂
• Molecular Weight: 1143.41
• Mol file: 63264-36-8.mol

Synonyms:

Chemical Property of [Ir((CH₃)3CS)(CO)(P(C₆H₅)3)]2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [Ir((CH₃)3CS)(CO)(P(C₆H₅)3)]2

There total 1 articles about [Ir((CH₃)3CS)(CO)(P(C₆H₅)3)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[Ir2(CO)4(μ-SC(CH3)3)2] (63312-27-6) → {Ir(μ-SBu**t)(CO)(PPh3)} + [Ir((CH3)3CS)(CO)(P(C6H5)3)]2 (63264-36-8) + [Ir2(μ-SBu-t)2(CO)3(PPh3)]

Guidance literature:

With triphenylphosphine; In toluene; pentane; byproducts: CO; addn. of soln. of 2 equiv. of PPh3 in pentane to soln. of complex in toluene, crystn. at -20°C, under dry O2-free N2; elem. anal.;

DOI:10.1016/S0022-328X(00)93824-5

Reference yield: 83.0%

[Ir((CH3)3CS)(CO)(P(C6H5)3)]2 (63264-36-8) + diiodomethane (75-11-6) → [IrI((CH3)3CS)(CO)(P(C6H5)3)]2(CH2) (94890-46-7)

Guidance literature:

In dichloromethane; (N2 or Ar), CH2I2 added to a soln. of the Ir-complex, few minutes; concd. under vacuum, hexane added dropwise, mother liquor decanted, washed with hexane, dried under vacuum, recrystd. from CH2Cl2/CH3OH, elem. anal.;

Reference yield:

[Ir((CH3)3CS)(CO)(P(C6H5)3)]2 (63264-36-8) + 1,1-dibromomethane (74-95-3) → [IrBr((CH3)3CS)(CO)(P(C6H5)3)]2(CH2) (94904-36-6)

Guidance literature:

In dichloromethane; (N2 or Ar), CH2Br2 added to a soln. of the Ir-complex, 25 h; concd. under vacuum, hexane added dropwise, mother liquor decanted, washed with hexane, dried under vacuum, recrystd. from CH2Cl2/CH3OH, yield detected by IR;

upstream raw materials:

[Ir2(CO)4(μ-SC(CH3)3)2]

Downstream raw materials:

[IrI((CH₃)3CS)(CO)(P(C₆H₅)3)]2(CH₂)

[IrBr((CH₃)3CS)(CO)(P(C₆H₅)3)]2(CH₂)