Technology Process of η5-monodeuterocyclopentadienyldicarbonyliron(II)-η1,η5-cyclopentadienyldicarbonyltriphenylphosphinemanganese(I)
There total 1 articles about η5-monodeuterocyclopentadienyldicarbonyliron(II)-η1,η5-cyclopentadienyldicarbonyltriphenylphosphinemanganese(I) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
n-butyllithium;
In
tetrahydrofuran; hexane;
under Ar; soln. of n-BuLi in hexane added to soln. of Fe-Mn complex in THF at -78°C; stirred (-78°C, 1.5 h); D2O added; stirred (-78°C, 30 min); warmed to 20°C; solvent removed; chromd. (Al2O3, benzene-hexane 1:1);
DOI:10.1007/s11172-006-0334-8
