Diisopropyl adipate

Base Information

• Chemical Name: Diisopropyl adipate
• CAS No.: 121879-14-9
• Molecular Formula: C₁₂H₂₂O₄
• Molecular Weight: 230.304
• Mol file: 121879-14-9.mol

Synonyms:

Chemical Property of Diisopropyl adipate

Chemical Property:

• Vapor Pressure: 0.0192mmHg at 25°C

Purity/Quality:

≥95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Diisopropyl adipate

There total 16 articles about Diisopropyl adipate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

hexanedioic acid dimethyl ester (627-93-0) + isopropyl alcohol (67-63-0,8013-70-5) → adipic acid diisopropyl ester (6938-94-9,121879-14-9)

Guidance literature:

With tetramethylammonium methyl carbonate; for 8h; Molecular sieve; Reflux; Green chemistry;

DOI:10.1039/c7gc03858e

Reference yield: 89.0%

Adipic acid (124-04-9) + isopropyl alcohol (67-63-0,8013-70-5) → adipic acid diisopropyl ester (6938-94-9,121879-14-9)

Guidance literature:

With thionyl chloride; sodium carbonate; for 2h; Heating;

DOI:10.1080/10426500490459812

Reference yield: 88.0%

carbon monoxide (201230-82-2) + diisopropyl (E)-hex-3-enedioate (90157-48-5) → adipic acid diisopropyl ester (6938-94-9,121879-14-9) + diisopropyl 3-formylhexanedioate

Guidance literature:

With triphenyl phosphite; (acetylacetonato)dicarbonylrhodium (l); hydrogen; In tetrahydrofuran; at 70 ℃; for 16h; under 3750.38 - 15001.5 Torr; Schlenk technique; Autoclave;

DOI:10.1021/acs.joc.6b02939

upstream raw materials:

2-nitrocyclohexanone

isopropyl alcohol

Adipic acid

2,4-dinitro-benzenesulfonic acid 2-oxo-cyclohexyl ester

Refernces

• 1、 Dermeche, Leila,Idrissou, Yasmina,Mazari, Tassadit,Moudjahed, Mohammed,Rabia, Cherifa. "Oxidation of cyclohexanone and/or cyclohexanol catalyzed by Dawson-type polyoxometalates using hydrogen peroxide". . . Retrieved 2022/03/07.
• 2、 Yang, Ji,Liu, Jiawang,Ge, Yao,Huang, Weiheng,Ferretti, Francesco,Neumann, Helfried,Jiao, Haijun,Franke, Robert,Jackstell, Ralf,Beller, Matthias. "Efficient Palladium-Catalyzed Carbonylation of 1,3-Dienes: Selective Synthesis of Adipates and Other Aliphatic Diesters". supporting information. p. 9527 - 9533. Retrieved 2021/03/08.