2-phenylbicyclo<2.1.1>hex-2-ene

Base Information

• Chemical Name: 2-phenylbicyclo<2.1.1>hex-2-ene
• CAS No.: 126109-97-5
• Molecular Formula: C₁₂H₁₂
• Molecular Weight: 156.227
• Mol file: 126109-97-5.mol

Synonyms:

Chemical Property of 2-phenylbicyclo<2.1.1>hex-2-ene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-phenylbicyclo<2.1.1>hex-2-ene

There total 5 articles about 2-phenylbicyclo<2.1.1>hex-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,5-hexadiene-3-ol (924-41-4) → 2-phenylbicyclo<2.1.1>hex-2-ene (126109-97-5)

Guidance literature:

Multi-step reaction with 4 steps

1: chromium trioxide, sulfuric acid / H₂O; acetone; benzene / 0.25 h / 0 °C

2: pentane / 24 h / Irradiation

3: magnesium / in THF

4: 1) sodium hydride (50percent), 2) carbon disulfide, 3) methyl iodide / 1) ether, 15 min, 2) 0.5 h, reflux, 3) 12 h, reflux

With chromium(VI) oxide; carbon disulfide; sulfuric acid; sodium hydride; magnesium; methyl iodide; In water; acetone; pentane; benzene;

DOI:10.1021/jo00289a053

Reference yield:

hexa-1,5-dien-3-one (6857-93-8) → 2-phenylbicyclo<2.1.1>hex-2-ene (126109-97-5)

Guidance literature:

Multi-step reaction with 3 steps

1: pentane / 24 h / Irradiation

2: magnesium / in THF

3: 1) sodium hydride (50percent), 2) carbon disulfide, 3) methyl iodide / 1) ether, 15 min, 2) 0.5 h, reflux, 3) 12 h, reflux

With carbon disulfide; sodium hydride; magnesium; methyl iodide; In pentane;

DOI:10.1021/jo00289a053

Reference yield:

2-hydroxy-2-phenylbicyclo<2.1.1>hexane (125642-76-4) → 2-phenylbicyclo<2.1.1>hex-2-ene (126109-97-5)

Guidance literature:

With carbon disulfide; sodium hydride; methyl iodide; Yield given. Multistep reaction; 1) ether, 15 min, 2) 0.5 h, reflux, 3) 12 h, reflux;

DOI:10.1021/jo00289a053

upstream raw materials:

2-hydroxy-2-phenylbicyclo<2.1.1>hexane

bromobenzene

1,5-hexadiene-3-ol

hexa-1,5-dien-3-one

Downstream raw materials:

3-phenylbicyclo<3.1.0>hex-2-ene

2-phenylbicyclo<3.1.0>hex-2-ene

1-phenylbicyclo<3.1.0>hex-2-ene

3-benzoylcyclobutanecarboxaldehyde