Stannane, tributyl[1-(phenylmethyl)-1-propenyl]-, (E)-

Base Information

Chemical Name:Stannane, tributyl[1-(phenylmethyl)-1-propenyl]-, (E)-
CAS No.:130826-42-5
Molecular Formula:C₂₂H₃₈Sn
Molecular Weight:421.254
Hs Code.:

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Chemical Property of Stannane, tributyl[1-(phenylmethyl)-1-propenyl]-, (E)-

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Technology Process of Stannane, tributyl[1-(phenylmethyl)-1-propenyl]-, (E)-

There total 2 articles about Stannane, tributyl[1-(phenylmethyl)-1-propenyl]-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: bis(tributylstannyl)lithium(cuprate)

: 32644-22-7,70000-51-0,62014-64-6,2327-98-2
1-methyl-3-phenylallene

: 156666-66-9,130826-42-5
CH₃CHC(CH₂C₆H₅)(tributylstannyl)

Guidance literature:: With ammonium chloride; In tetrahydrofuran; React. of starting materials (THF, -78 to 0°C, 1 h).;
DOI:10.1039/c39900001030

Reference yield: 78.0%

: Schwartz's reagent

: 100-39-0
benzyl bromide

: 64099-82-7
1-propynyltributylstannane

: 130826-42-5,156666-66-9
C₆H₅CH₂C(Sn(C₄H₉)3)CHCH₃

Guidance literature:: With methyllithium; In tetrahydrofuran; addn. of CH3CCSnBu3 (0.15 mmol) to a stirred suspension of Zr(C5H5)2(H)Cl (0.17 mmol) in THF; cooling to -78°C; addn. of 2-thienyl cyanocuprate (0.17 mmol) in THF and CH3Li (0.34 mmol) in ether; addn. of C6H5CH2Br (0.23 mmol) after 10 min;; pouring into 10% aq. NaHCO3 soln. after 2 h at -78°C; sepn. of org. layer; extn. with ether; drying the combined org. layers (MgSO4) after washing with brine; filtering through Celite, concg. (vac.); chromy. (silica gel); IR, NMR, mass spectum;;
DOI:10.1016/0020-1693(94)03852-X