1'-(diphenylphosphinoyl)-1-hydroxyferrocene

Base Information

Chemical Name:1'-(diphenylphosphinoyl)-1-hydroxyferrocene
CAS No.:729610-15-5
Molecular Formula:C₂₂H₁₉FeO₂P
Molecular Weight:402.212
Hs Code.:

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Chemical Property of 1'-(diphenylphosphinoyl)-1-hydroxyferrocene

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Technology Process of 1'-(diphenylphosphinoyl)-1-hydroxyferrocene

There total 2 articles about 1'-(diphenylphosphinoyl)-1-hydroxyferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 5796-98-5
bis-trimethylsilanyl peroxide

: 185224-06-0
1-bromo-1'-(diphenylphosphinoyl)ferrocene

: 729610-15-5
1'-(diphenylphosphinoyl)-1-hydroxyferrocene

Guidance literature:: With C₄H₉Li; In tetrahydrofuran; hexane; (Schlenk technique); addn. of hexane soln. of butyllithium to THF soln. of ferrocene deriv. at -78°C, stirring at -78°C for 10 min, addn. of peroxide deriv., stirring at -78°C for 1 h; evapn., treatment with water, chromy. (silica, ethyl acetate/hexane (2:1));
DOI:10.1039/c0dt00061b

Reference yield: 21.0%

: 1293-65-8
1,1'-dibromoferrocene

: 7732-18-5
water

: 729610-15-5
1'-(diphenylphosphinoyl)-1-hydroxyferrocene

Guidance literature:: With n-butyllithium; bis(trimethylsilyl)peroxide; air; In tetrahydrofuran; (N2); using Schlenk techniques; addn. of BuLi/C6H14 to Fe(C5H4Br)2/THF at -78°C; stirring for 10 min; addn. of (TMSO)2; stirring for 1 h;warming to room temp., removal of solvent, dissolving in Et2O; addn. of air-satd.H2O; stirring for 15 h (N2); sepn., extn. of org. layer with water, acidifying of combined aq. layersto pH = 1 with concd. HCl; extn. into Et2O; sepn. of layers; washing of org. layer with water, drying (Na2SO4); removal of solvent in vac., cry stn.; elem. anal.;
DOI:10.1039/b403862b

Reference yield: 46.0%

: 729610-15-5
1'-(diphenylphosphinoyl)-1-hydroxyferrocene

: titanium(IV) chloride tetrahydrofuran

: 1246843-62-8
bis[1-(diphenylphosphanyloxy-κO)-1'-(oxo-κO)ferrocene]dichlorotitanium(IV)

Guidance literature:: In dichloromethane; (Schlenk technique); addn. of CH2Cl2 soln. of ferrocene deriv. to dry CH2Cl2 soln. of titanium compd., stirring at room temp. for 15 hs; evapn., washing with dry pentane, filtration, drying in vac., elem. anal.;
DOI:10.1039/c0dt00061b