Bis(trimethylsilyl)peroxide

Base Information

Chemical Name:Bis(trimethylsilyl)peroxide
CAS No.:5796-98-5
Molecular Formula:C6H18O2Si2
Molecular Weight:178.379
Hs Code.:29319090
DSSTox Substance ID:DTXSID60434842
Nikkaji Number:J433.886C
Wikipedia:Bis(trimethylsilyl)peroxide
Wikidata:Q50052005
Mol file:5796-98-5.mol

Synonyms:bis(trimethylsilyl) peroxide

Suppliers and Price of Bis(trimethylsilyl)peroxide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Bis(trimethylsilyl)peroxide~50%inHMDS
250mg
$ 1050.00

TRC
Bis(trimethylsilyl)peroxide~50%inHMDS
100mg
$ 475.00

American Custom Chemicals Corporation
BIS-(TRIMETHYLSILYL)PEROXIDE 95.00%
100G
$ 1323.00

American Custom Chemicals Corporation
BIS-(TRIMETHYLSILYL)PEROXIDE 95.00%
10G
$ 522.81

American Custom Chemicals Corporation
BIS-(TRIMETHYLSILYL)PEROXIDE 95.00%
5MG
$ 504.66

Total 28 raw suppliers

Chemical Property of Bis(trimethylsilyl)peroxide

Chemical Property:

Vapor Pressure:15.267mmHg at 25°C
Melting Point:< 0 °C
Refractive Index:1.395
Boiling Point:124.639 °C at 760 mmHg
Flash Point:20.542 °C
PSA：18.46000
Density:0.842 g/cm³
LogP:2.60440
Storage Temp.:below 5° C
Solubility.:highly sol aprotic organic solvents.
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:178.08453288
Heavy Atom Count:10
Complexity:87.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bis(trimethylsilyl)peroxide~50%inHMDS ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 8-10
Safety Statements: 17-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)OO[Si](C)(C)C
Physical properties bp 41°C/30 mmHg;7 n20 D 1.3970.
Uses Bis(trimethylsilyl) peroxide (1) functions as an electrophilic hydroxylating agent for aliphatic, aromatic, and heteroaromatic anions.Reaction of their lithium or Grignard compounds with (1) often affords trimethylsiloxy intermediates, which undergo desilylation with HCl in methanol to give the corresponding alcohols in good yields. In the presence of a catalytic amount of trifluoromethanesulfonic acid, (1) reacts with aromatic compounds to produce the corresponding phenols after acidic workup.In these reactions the Me3SiO? moiety is considered as a synthon of the hydroxyl cation (i.e. OH+). Bis(trimethylsilyl) peroxide is an organosilicon compound used as a reagent for Bayer-Villiger oxidation of ketones.

Technology Process of Bis(trimethylsilyl)peroxide

There total 1 articles about Bis(trimethylsilyl)peroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: