(4-chlorophenyl)methanediyl diacetate

Base Information

• Chemical Name: (4-chlorophenyl)methanediyl diacetate
• CAS No.: 13086-93-6
• Molecular Formula: C11H11ClO4
• Molecular Weight: 242.659
• Mol file: 13086-93-6.mol

Synonyms:

Chemical Property of (4-chlorophenyl)methanediyl diacetate

Chemical Property:

• Vapor Pressure: 0.000302mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (4-chlorophenyl)methanediyl diacetate

There total 9 articles about (4-chlorophenyl)methanediyl diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

acetic anhydride (108-24-7) + 4-chlorobenzaldehyde (104-88-1) → (acetyloxy)(4-chlorophenyl)methyl acetate (13086-93-6)

Guidance literature:

With poly(4-vinylpyridine)-supported sulfuric acid; In dichloromethane; at 20 ℃; for 0.0833333h; chemoselective reaction; Green chemistry;

DOI:10.1080/00397911.2011.635258

Reference yield: 90.0%

2-(4-chlorophenyl)-5,5-dimethyl-1,3-dioxane (6283-10-9) + ethane-1,2-dithiol (540-63-6) → (acetyloxy)(4-chlorophenyl)methyl acetate (13086-93-6)

Guidance literature:

With 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane tribromide; In acetonitrile; at 20 ℃; for 2h;

Reference yield: 82.0%

4-chlorobenzaldehyde dimethyl acetal (3395-81-1) + acetic anhydride (108-24-7) → (acetyloxy)(4-chlorophenyl)methyl acetate (13086-93-6) + 4-chlorobenzaldehyde (104-88-1)

Guidance literature:

With titanium(IV) fluoride; at 20 ℃; for 24h; screw-capped vial; Inert atmosphere; neat (no solvent);

DOI:10.1055/s-0029-1218849

upstream raw materials:

4-chlorobenzaldehyde

acetic anhydride

6-(4-Chloro-phenyl)-6,7-dihydro-5H-5,7,7a,13-tetraaza-benzo[3,4]cyclohepta[1,2-b]naphthalen-8-one

para-chlorotoluene

Downstream raw materials:

2,2,2-trichloro-1-(4-chloro-phenyl)-ethanol

4-chlorobenzaldehyde

4-Cyanochlorobenzene

1-(4-chlorophenyl)-3-butenyl acetate