Benzenesulfinyl chloride, 4-nitro-

Base Information

• Chemical Name: Benzenesulfinyl chloride, 4-nitro-
• CAS No.: 13088-17-0
• Molecular Formula: C6H4ClNO3S
• Molecular Weight: 205.622
• Mol file: 13088-17-0.mol

Synonyms:

Chemical Property of Benzenesulfinyl chloride, 4-nitro-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenesulfinyl chloride, 4-nitro-

There total 11 articles about Benzenesulfinyl chloride, 4-nitro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

N-amino(p-nitrophenyl)dichlorosulfurane (101414-51-1) → 4-nitro-benzenesulfinyl chloride (13088-17-0) + ethyl benzimidate hydrochloride (5333-86-8)

Guidance literature:

With formic acid; In benzene; at 20 ℃; for 16h;

Reference yield: 76.0%

N-(diethoxymethylene)amino(p-nitrophenyl)dichlorosulfurane (101414-49-7) → 4-nitro-benzenesulfinyl chloride (13088-17-0)

Guidance literature:

With formic acid; In benzene; at 20 ℃; for 16h;

Reference yield:

N-(4-nitro-phenylsulfanylmethyl)-phthalimide (71858-47-4) → N-(chloromethyl)phthalimide (17564-64-6) + 4-nitro-benzenesulfinyl chloride (13088-17-0)

Guidance literature:

With acetic anhydride; chlorine; In tetrachloromethane; for 2h; Yield given; Ambient temperature;

upstream raw materials:

di(p-nitrophenyl) disulfide

N-(4-nitro-phenylsulfanylmethyl)-phthalimide

N-(diethoxymethylene)amino(p-nitrophenyl)dichlorosulfurane

N-amino(p-nitrophenyl)dichlorosulfurane

Downstream raw materials:

4-Nitro-benzenesulfinic acid 1-chloro-1-morpholin-4-yl-meth-(Z)-ylideneamide

4-Nitro-benzenesulfinyl isocyanate

[2,2]bipyridinyl

Refernces

• 1、 Izzo, Flavia,Sch?fer, Martina,Stockman, Robert,Lücking, Ulrich. "A New, Practical One-Pot Synthesis of Unprotected Sulfonimidamides by Transfer of Electrophilic NH to Sulfinamides". supporting information. p. 15189 - 15193. Retrieved 2017/10/12.
• 2、 Liang, Chungen,Collet, Florence,Robert-Peillard, Fabien,Mueller, Paul,Dodd, Robert H.,Dauban, Philippe. "Toward a synthetically useful stereoselective C-H amination of hydrocarbons". . p. 343 - 350. Retrieved 2008/10/09.