6-Bromo-6'-methyl-2,2'-bipyridine

Base Information

Chemical Name:6-Bromo-6'-methyl-2,2'-bipyridine
CAS No.:130897-00-6
Molecular Formula:C11H9BrN2
Molecular Weight:249.11
Hs Code.:
DSSTox Substance ID:DTXSID20563980
Nikkaji Number:J2.182.032F
Wikidata:Q82448542

Synonyms:6-Bromo-6'-methyl-2,2'-bipyridine;130897-00-6;2-bromo-6-(6-methylpyridin-2-yl)pyridine;2,2'-Bipyridine, 6-bromo-6'-methyl-;2-(6-bromopyridin-2-yl)-6-methylpyridine;SCHEMBL3419835;DTXSID20563980;NXGNPPRIURACGI-UHFFFAOYSA-N;A903211

Suppliers and Price of 6-Bromo-6'-methyl-2,2'-bipyridine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 7 raw suppliers

Chemical Property of 6-Bromo-6'-methyl-2,2'-bipyridine

Chemical Property:

XLogP3:2.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:247.99491
Heavy Atom Count:14
Complexity:186

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=NC(=CC=C1)C2=NC(=CC=C2)Br

Technology Process of 6-Bromo-6'-methyl-2,2'-bipyridine

There total 9 articles about 6-Bromo-6'-methyl-2,2'-bipyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 626-05-1
2,6-Dibromopyridine

: 126225-57-8
6-methyl-2-(trimethylstannyl)pyridine

: 130897-00-6
6-bromo-6′-methyl-2,2′-bipyridine

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; lithium chloride; In toluene; at 120 ℃; for 24h;
DOI:10.1016/j.tet.2005.03.131

Reference yield: 44.0%

: 5315-25-3
2-bromo-6-methylpyridine

: C₅H₃BrClMgN*ClLi

: 130897-00-6
6-bromo-6′-methyl-2,2′-bipyridine

Guidance literature:: 2-bromo-6-methylpyridine; With magnesium; In tetrahydrofuran; at 20 ℃; for 0.5h; Inert atmosphere;

With isopropylsulfinyl chloride; In tetrahydrofuran; at -20 - 20 ℃; for 1h; Inert atmosphere;

C₅H₃BrClMgN*ClLi; In tetrahydrofuran; at -78 - 20 ℃; for 0.5h; Inert atmosphere;
DOI:10.1002/anie.201915425