[η⁵-1,2,4-(Me3C)3C5H2]2Th=N(p-tolyl)

Base Information

• Chemical Name: [η⁵-1,2,4-(Me3C)3C5H2]2Th=N(p-tolyl)
• CAS No.: 1323150-26-0
• Molecular Formula: C₄₁H₆₅NTh
• Molecular Weight: 804.012
• Mol file: 1323150-26-0.mol

Synonyms:

Chemical Property of [η⁵-1,2,4-(Me3C)3C5H2]2Th=N(p-tolyl)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [η⁵-1,2,4-(Me3C)3C5H2]2Th=N(p-tolyl)

There total 4 articles about [η⁵-1,2,4-(Me3C)3C5H2]2Th=N(p-tolyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

(η5-1,2,4-(Me3C)3C5H2)2ThMe2 (1323150-18-0) + [η5-1,2,4-(Me3C)3C5H2]2Th(NH-p-tolyl)2 (1323150-22-6) → [η5-1,2,4-(Me3C)3C5H2]2Th=N(p-tolyl) (1323150-26-0)

Guidance literature:

In toluene; (N2) mixt. Th complexes in toluene was refluxed for 4 days; soln. was filtered, concd. and cooled to -20°C; elem. anal.;

DOI:10.1021/ja205280k

Reference yield:

[η5-1,2,4-(Me3C)3C5H2]2Th(NH-p-tolyl)2 (1323150-22-6) → [η5-1,2,4-(Me3C)3C5H2]2Th=N(p-tolyl) (1323150-26-0)

Guidance literature:

at 140 ℃; under 0.01 Torr;

DOI:10.1021/acs.organomet.5b00454

Reference yield:

p-methylazidobenzene (2101-86-2) + [η5-1,2,4-(Me3C)3C5H2]2Th(bipy) → [η5-1,2,4-(Me3C)3C5H2]2Th=N(p-tolyl) (1323150-26-0)

Guidance literature:

In benzene-d6; byproducts: (C5H4N)2, N2; (N2); a soln. of CH3C6H4N3 added slowly to Th complex in benzene-d6; not isolated, detected by NMR;

DOI:10.1021/om201015f

upstream raw materials:

(η⁵-1,2,4-(Me3C)3C5H2)2ThMe2

[η⁵-1,2,4-(Me₃C)₃C₅H₂]2Th(NH-p-tolyl)₂

p-methylazidobenzene

Downstream raw materials:

[η5-1,2,4-(Me3C)3C5H2]2Th[(μ-O)2CPh2]

[η5-1,2,4-(Me3C)3C5H2]2Th[N(p-tolyl)C(NPh)-S]

[η5-1,2,4-(Me3C)3C5H2]2Th[(μ-S)2CPh2]

[η⁵-1,2,4-(Me₃C)₃C₅H₂]2Th(NH-p-tolyl)₂