hexahydro(μ-([P(S),P'(S)]-[1,3-phenylenebis(methylene)]bis[isopropyl(phenyl)phosphine-κP]))diboron

Base Information

Chemical Name:hexahydro(μ-([P(S),P'(S)]-[1,3-phenylenebis(methylene)]bis[isopropyl(phenyl)phosphine-κP]))diboron
CAS No.:852720-30-0
Molecular Formula:C₂₆H₃₈B₂P₂
Molecular Weight:434.157
Hs Code.:

Synonyms:

Suppliers and Price of hexahydro(μ-([P(S),P'(S)]-[1,3-phenylenebis(methylene)]bis[isopropyl(phenyl)phosphine-κP]))diboron

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of hexahydro(μ-([P(S),P'(S)]-[1,3-phenylenebis(methylene)]bis[isopropyl(phenyl)phosphine-κP]))diboron

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of hexahydro(μ-([P(S),P'(S)]-[1,3-phenylenebis(methylene)]bis[isopropyl(phenyl)phosphine-κP]))diboron

There total 1 articles about hexahydro(μ-([P(S),P'(S)]-[1,3-phenylenebis(methylene)]bis[isopropyl(phenyl)phosphine-κP]))diboron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

: 565232-59-9
trihydro[isopropyl(phenyl)phosphine]boron

: 626-15-3
1,3-bis-(bromomethyl)benzene

: 852720-30-0
hexahydro(μ-([P(S),P'(S)]-[1,3-phenylenebis(methylene)]bis[isopropyl(phenyl)phosphine-κP]))diboron

Guidance literature:: With BuLi; (-)-sparteine; In diethyl ether; hexane; under N2 atm. BuLi in hexane was added to soln. phosphine-borane complexin Et2O at -78°C, stirred for 15 min, (-)-sparteine was added, w armed to r.t. and warmed to 30°C for 1 h, cooled to -78°C,1,3-C6H4(CH2Br)2 was added, 3 h; after cooling in freezer (-30°C) overnight, 5 % H2SO4 was added, aq. layer was washed with CH2Cl2, org. phase was evapd., residue was wshed with hexane-Et2O (3:1); elem. anal.;
DOI:10.1002/hlca.200590048

Reference yield: 16.0%

: 161929-65-3
((C₆H₃(CH₂N(CH₃)2)2)RuCl(P(C₆H₅)3))

: 852720-30-0
hexahydro(μ-([P(S),P'(S)]-[1,3-phenylenebis(methylene)]bis[isopropyl(phenyl)phosphine-κP]))diboron

: 852720-34-4
(2,6-bis(([P(S)]-isopropyl(phenyl)phosphino-κP)methyl)phenyl-κC)chloro(triphenylphosphine)ruthenium

Guidance literature:: With Et₂NH; In benzene; under N2 atm. phosphine-borane was heated overnight (45°C) in benzene, Ru complex was addedand heated for 48 h; volatiles were removed under high vac., residue was washed with cold pentane, dissolved in Et2O, filtereed and evapd.; elem. anal.;
DOI:10.1002/hlca.200590048