Technology Process of 2-Phenylthio-1,2-dehydro-x-cyperon
There total 5 articles about 2-Phenylthio-1,2-dehydro-x-cyperon which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 180 mg / pyridinium chlorochromate (PCC) / CH2Cl2 / 2 h / Ambient temperature
2: 1.) lithium diisopropylamide (LDA) / 1.) THF, hexane, -78 deg C, 50 min., 2.) THF, hexane, RT, 1 h
With
pyridinium chlorochromate; lithium diisopropyl amide;
In
dichloromethane;
DOI:10.1246/bcsj.55.1195
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 95 mg / sodium borohydride / methanol / 1.5 h / -50 - -45 °C
2: 203 mg / VO(acac)2, t-butyl hydroperoxide / benzene / 0.17 h / Heating
3: 180 mg / pyridinium chlorochromate (PCC) / CH2Cl2 / 2 h / Ambient temperature
4: 1.) lithium diisopropylamide (LDA) / 1.) THF, hexane, -78 deg C, 50 min., 2.) THF, hexane, RT, 1 h
With
tert.-butylhydroperoxide; sodium tetrahydroborate; bis(acetylacetonate)oxovanadium; pyridinium chlorochromate; lithium diisopropyl amide;
In
methanol; dichloromethane; benzene;
DOI:10.1246/bcsj.55.1195
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 203 mg / VO(acac)2, t-butyl hydroperoxide / benzene / 0.17 h / Heating
2: 180 mg / pyridinium chlorochromate (PCC) / CH2Cl2 / 2 h / Ambient temperature
3: 1.) lithium diisopropylamide (LDA) / 1.) THF, hexane, -78 deg C, 50 min., 2.) THF, hexane, RT, 1 h
With
tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; pyridinium chlorochromate; lithium diisopropyl amide;
In
dichloromethane; benzene;
DOI:10.1246/bcsj.55.1195
