N-OCTYLZINC BROMIDE

Base Information

• Chemical Name: N-OCTYLZINC BROMIDE
• CAS No.: 131379-13-0
• Molecular Formula: C8H17BrZn
• Molecular Weight: 258.517
• Mol file: 131379-13-0.mol

Synonyms:octylzinc bromide;n-Octylzinc bromide 0.5 M in Tetrahydrofuran;

Chemical Property of N-OCTYLZINC BROMIDE

Chemical Property:

• PSA: 0.00000
• LogP: 4.15760
• Sensitive.: Air Sensitive

Purity/Quality:

97% ^*data from raw suppliers

N-OCTYLZINC BROMIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-OCTYLZINC BROMIDE

There total 1 articles about N-OCTYLZINC BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-bromo-octane (111-83-1) + zinc (7440-66-6) → octylzinc(II) bromide (131379-13-0)

Guidance literature:

With LiCl; BrCH₂CH₂Br; (CH₃)3SiCl; In tetrahydrofuran; (N2); drying LiCl for 20 min (150-170°C, 1 mbar), addn. of Zn powder (1.4 equiv.), addn. of THF, activation by Br(CH2)2Br (5 %), Me3SiCl (1 %), addn. of C8H17Br at room temp., storage for 24 h; Angew. Chem., Int. Ed., 2006, 45, 6040;

DOI:10.1039/c1ob06071f

Reference yield: 95.0%

octylzinc(II) bromide (131379-13-0) → octanol (111-87-5)

Guidance literature:

With titanium(IV) isopropylate; tert.-butylhydroperoxide; In diethyl ether; at -78 ℃; for 12h;

DOI:10.1016/S0022-328X(00)00596-9

Reference yield: 91.0%

octylzinc(II) bromide (131379-13-0) + phenylacetylene (536-74-3) → 1-phenyl-1-decyne (16664-50-9)

Guidance literature:

With carbon monoxide; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In tetrahydrofuran; at 20 ℃; for 24h; under 760.051 Torr;

DOI:10.1021/ja100630p

upstream raw materials:

1-bromo-octane

zinc

Downstream raw materials:

octanol

Hexadecane

octane

1,4-diphenyl-1,3-butadiyne