CID 6100334

Base Information

Chemical Name:CID 6100334
CAS No.:131379-38-9
Molecular Formula:C9H9BrO2Zn
Molecular Weight:294.463
Hs Code.:
DSSTox Substance ID:DTXSID20449376

Synonyms:Zinc, bromo[3-(ethoxycarbonyl)phenyl]-;DTXSID20449376

Suppliers and Price of CID 6100334

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of CID 6100334

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:291.90773
Heavy Atom Count:13
Complexity:236

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1=CC=C[C-]=C1.[Zn+]Br

Technology Process of CID 6100334

There total 2 articles about CID 6100334 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 24398-88-7
ethyl 3-bromobenzoate

: 7440-66-6
zinc

: 131379-38-9
(3-(ethoxycarbonyl)phenyl)zinc(II) bromide

Guidance literature:: In tetrahydrofuran; other Radiation; microwave-accelerated preparation of arylzinc bromide by Rieke zinc insertion into aryl bromide under sealed vessel conditions for 30 min; THF 180°C; HPLC or MS;
DOI:10.1039/b313887a

Reference yield:

: 58313-23-8
3-iodobenzoic acid methyl ester

: 7699-45-8
zinc dibromide

: 131379-38-9
(3-(ethoxycarbonyl)phenyl)zinc(II) bromide

Guidance literature:: 3-iodobenzoic acid methyl ester; With isopropylmagnesium bromide; In tetrahydrofuran; at -30 ℃; for 0.5h;

zinc dibromide; In tetrahydrofuran;
DOI:10.15227/orgsyn.079.0035

Reference yield: 91.0%

: 35761-91-2
5-iodo-1-trimethylsilyl-1-pentyne

: 131379-38-9
(3-(ethoxycarbonyl)phenyl)zinc(II) bromide

: ethyl 3-[5-(trimethylsilyl)pent-4-ynyl]benzoate

Guidance literature:: (3-(ethoxycarbonyl)phenyl)zinc(II) bromide; With (trimethylsilyl)methylmagnesium chloride; In tetrahydrofuran; diethyl ether; at 0 ℃; for 1h;

5-iodo-1-trimethylsilyl-1-pentyne; With N,N,N,N,-tetramethylethylenediamine; iron(III) chloride; In tetrahydrofuran; at 30 ℃; for 6h;
DOI:10.1055/s-2005-871541