(η3-pentadienyl)ruthenium(chloride)(dimethylphenylphosphine)3

Base Information

• Chemical Name: (η3-pentadienyl)ruthenium(chloride)(dimethylphenylphosphine)3
• CAS No.: 116026-14-3
• Molecular Formula: C₂₉H₄₀ClP₃Ru
• Molecular Weight: 618.081
• Mol file: 116026-14-3.mol

Synonyms:

Chemical Property of (η3-pentadienyl)ruthenium(chloride)(dimethylphenylphosphine)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η3-pentadienyl)ruthenium(chloride)(dimethylphenylphosphine)3

There total 1 articles about (η3-pentadienyl)ruthenium(chloride)(dimethylphenylphosphine)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

(η5-pentadienyl)ruthenium(chloride)(dimethylphenylphosphine)(triphenylphosphine) (116026-06-3) + Dimethyl(phenyl)phosphine (672-66-2) → (η3-pentadienyl)ruthenium(chloride)(dimethylphenylphosphine)3 (116026-14-3)

Guidance literature:

In toluene; Addn. of PMe2Ph to cryst. of Ru-compd. (toluene, N2), refluxing (1 h) during which soln.' color changes from orange to yellow-orange, cooling of mixt. (room temp.) and stirring (72 h) causes pptn. of yellow solid.; Removal of solvent (vac.), extn. of yielded oil (THF), cooling (-30°C), filtn. of resulting powder, washing (pentane), drying. Elem. anal.;

DOI:10.1021/om00101a013

Reference yield: 98.0%

(η3-pentadienyl)ruthenium(chloride)(dimethylphenylphosphine)3 (116026-14-3) + silver trifluoromethanesulfonate (2923-28-6) → {(η5-pentadienyl)ruthenium(dimethylphenylphosphine)3}(trifluoromethanesulfonate) (116026-18-7)

Guidance literature:

In dichloromethane; Addn. of Ag-compd. to cold (-78°C), stirred soln. of Ru-compd. (CH2Cl2) under N2, warming to 20°C during which soln. turns bright red and then pale yellow as a white ppt. formes.; Filtn., drying (vac.), elem. anal.;

DOI:10.1021/om00101a013

upstream raw materials:

(η5-pentadienyl)ruthenium(chloride)(dimethylphenylphosphine)(triphenylphosphine)

Dimethyl(phenyl)phosphine

Downstream raw materials:

{(η5-pentadienyl)ruthenium(dimethylphenylphosphine)3}(trifluoromethanesulfonate)