trans-(±)-4-(acetoxy)cyclohex-2-en-1-yl acetate

Base Information

• Chemical Name: trans-(±)-4-(acetoxy)cyclohex-2-en-1-yl acetate
• CAS No.: 135615-69-9
• Molecular Formula: C₁₀H₁₄O₄
• Molecular Weight: 198.219
• Mol file: 135615-69-9.mol

Synonyms:

Chemical Property of trans-(±)-4-(acetoxy)cyclohex-2-en-1-yl acetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-(±)-4-(acetoxy)cyclohex-2-en-1-yl acetate

There total 13 articles about trans-(±)-4-(acetoxy)cyclohex-2-en-1-yl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

acetic acid (64-19-7,77671-22-8) + cyclohexa-1,3-diene (1165952-91-9) → trans-(±)-4-(acetoxy)cyclohex-2-en-1-yl acetate (78776-44-0,20117-77-5,78776-45-1,135615-69-9)

Guidance literature:

With manganese(IV) oxide; palladium diacetate; lithium acetate; p-benzoquinone; In pentane; for 8h; Ambient temperature; other 1,3-Dienes;

DOI:10.1021/jo00198a010

Reference yield: 87.0%

acetic acid (64-19-7,77671-22-8) + cyclohexa-1,3-diene (1165952-91-9) → cis-2-cyclohexenyl-1,4-diacetate (78776-45-1) + trans-(±)-4-(acetoxy)cyclohex-2-en-1-yl acetate (78776-44-0,20117-77-5,78776-45-1,135615-69-9)

Guidance literature:

With manganese(IV) oxide; lithium acetate; p-benzoquinone; palladium diacetate; In acetone; for 11h; Yields of byproduct given; Ambient temperature;

Reference yield: 85.0%

lithium acetate (546-89-4) + cyclohexa-1,3-diene (1165952-91-9) → trans-(±)-4-(acetoxy)cyclohex-2-en-1-yl acetate (78776-44-0,20117-77-5,78776-45-1,135615-69-9)

Guidance literature:

With oxygen; palladium diacetate; iron(II) phthalocyanine; 2-(phenylsulfinyl)-1,4-benzoquinone; In acetic acid; for 5.5h; under 760 Torr; Mechanism; Ambient temperature; or 1,4-hydroquinone/DMSO , other benzoquinones, time course of the reaction, stereoselectivity, other diene;

DOI:10.1021/jo00020a022

upstream raw materials:

acetic acid

cyclohexa-1,3-diene

lithium acetate

p-benzoquinone

Downstream raw materials:

trans-1,4-bis-(dicarbomethoxymethyl)cyclohex-2-ene

trans-2-cyclohexene-1,4-diol