hexakis[bis(2-aminoethoxy)methylsilylethyl]benzene

Base Information

• Chemical Name: hexakis[bis(2-aminoethoxy)methylsilylethyl]benzene
• CAS No.: 536755-19-8
• Molecular Formula: C₄₈H₁₁₄N₁₂O₁₂Si₆
• Molecular Weight: 1220.02
• Mol file: 536755-19-8.mol

Synonyms:

Chemical Property of hexakis[bis(2-aminoethoxy)methylsilylethyl]benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hexakis[bis(2-aminoethoxy)methylsilylethyl]benzene

There total 1 articles about hexakis[bis(2-aminoethoxy)methylsilylethyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

ethanolamine (141-43-5) + hexakis(methyldimethoxysilylethyl)benzene → hexakis[bis(2-aminoethoxy)methylsilylethyl]benzene (536755-19-8)

Guidance literature:

at 120 ℃; for 2h;

DOI:10.1023/A:1022199722015

Reference yield: 89.0%

cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) + hexakis[bis(2-aminoethoxy)methylsilylethyl]benzene (536755-19-8) → dodecachloro(hexakis[bis(2-aminoethoxy)methylsilylethyl]benzene)hexacobalt(II)

Guidance literature:

In acetonitrile; soln. of ligand in CH3CN was added to CoCl2; mixt. was stirred at 20°C for 1 h and at 80°C for 1 h; cooled; decanted; residue washed with CH3CN; solvent removed under vac.;elem. anal.;

DOI:10.1023/A:1022199722015

Reference yield: 36.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + hexakis[bis(2-aminoethoxy)methylsilylethyl]benzene (536755-19-8) → hexakis[bis(2-aminoethoxy)methylsilylethyl]benzenedicobalt(II) tetrakis(tetracarbonylcobaltate)

Guidance literature:

In diethyl ether; byproducts: CO; Co complex was added to soln. of ligand in ether; after 15 h mixt. washed with ether; repptd. with ether from soln. in CH3CN; elem. anal.;

DOI:10.1023/A:1022199722015

upstream raw materials:

ethanolamine