isocyanato(triphenylphosphine)gold(I)

Base Information

• Chemical Name: isocyanato(triphenylphosphine)gold(I)
• CAS No.: 24169-91-3
• Molecular Formula: C₁₉H₁₅AuNOP
• Molecular Weight: 501.274
• Mol file: 24169-91-3.mol

Synonyms:

Chemical Property of isocyanato(triphenylphosphine)gold(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of isocyanato(triphenylphosphine)gold(I)

There total 1 articles about isocyanato(triphenylphosphine)gold(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium cyanate (590-28-3) + (triphenylphosphine)gold(I) nitrate (14897-32-6) → isocyanato(triphenylphosphine)gold(I) (24169-91-3)

Guidance literature:

In methanol; dissolving KOCN in large ecess of methanol; addn. of soln. of Au(IP(C6H5)3NO3 in methanol; storage for 1 h;; addn. of H2O till pptn.; recrystn. by slow diffusion of hexane into CH2Cl2 soln.; elem. anal.; IR spectroscopy;;

Reference yield: 52.6%

PPh3AuIC8H5 (20224-83-3) + {(C6H5)3PAuMn(CO)5} (14692-78-5) + isocyanato(triphenylphosphine)gold(I) (24169-91-3) → ((C6H5)3PAu)3Mn(CO)4 (156429-18-4,59030-43-2)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); dissolving Ph3PAuMn(CO)5 (0.38 mmol), Ph3PAuNCO (0.38 mmol) and Ph3PAuN3 (0.12 mmmol) in freshly distd. THF; irradiation for 30 min with high-pressure-Hg-lamp;; evapn. to dryness; taking up residue in CH2Cl2, filtering; column chromy. (Al2O3, THF); elem. anal.;;

Reference yield: 30.0%

PPh3AuIC8H5 (20224-83-3) + isocyanato(triphenylphosphine)gold(I) (24169-91-3) + (C6H5)3PAuV(CO)6 (12114-33-9) → ((C6H5)3PAu)3V(CO)5 (78954-59-3) + {((C6H5)3PAu)6V(CO)4}(1+)*NCO(1-) = {((C6H5)3PAu)6V(CO)4}NCO

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); (N2), irradiated at room temp. for 15 min;; evapd. to dryness, dissolved in CH2Cl2, chromd. (Al2O3, CH2Cl2/EtOH), elem. anal.;

upstream raw materials:

potassium cyanate

(triphenylphosphine)gold(I) nitrate

Downstream raw materials:

((C₆H₅)3PAu)3Mn(CO)4

((C₆H₅)3PAu)3V(CO)5

{((C₆H₅)3PAu)6Mn(CO)3}⁽¹⁺⁾*PF₆^(1-) = {((C₆H₅)3PAu)6Mn(CO)3}PF₆