20224-83-3

Upstream product

• 14243-64-2 (triphenylphosphine)gold(I) chloride 
• 4648-54-8 trimethylsilylazide 
• 106734-50-3 (Ph₃P)gold(I)OtBu 

Downstream Products

• 15154-50-4 Co(carbonyl)4(PPh₃)gold 
• 139041-33-1 {((C₆H₅)3PAu)6Mn(CO)3}⁽¹⁺⁾*PF₆^(1-) = {((C₆H₅)3PAu)6Mn(CO)3}PF₆ 
• 156429-18-4 ((C₆H₅)3PAu)3Mn(CO)4 
• 78954-59-3 ((C₆H₅)3PAu)3V(CO)5 
• 922527-76-2 [(Ph₃P)Au(phenyltriazole)] 
• 922527-77-3 [(Ph₃P)Au(4-fluorophenyltriazole)] 

Relevant academic research and scientific papers

GOLD (I)-PHOSPHINE 1,2,3-TRIAZOLE DERIVATIVES WITH ANTIOBIOTIC PROPERTIES

The present invention relates to gold (l)-phosphine 1,2,3-triazole compounds, and their use in a human or animal medicine. The present invention also relates to using such compounds for the prevention and/or treatment of an infection, i.e. inhibitors of growth of Gram-positive and/or Gram-negative bacteria. On another aspect the invention relates to the synthesis of the gold (l)-phosphine compounds of the invention and to their synthesis intermediates. The present invention finds applications in the medical, veterinary and/or chemical fields.

METHOD OF PREPARATION OF URANIUM NITRIDE

Method for producing terminal uranium nitride complexes comprising providing a suitable starting material comprising uranium; oxidizing the starting material with a suitable oxidant to produce one or more uranium(IV)-azide complexes; and, sufficiently irr

Noble reactions for the actinides: Safe gold-based access to organouranium and azido complexes

A safe gold-based oxidative functionalization protocol has been developed, which allows access to an assortment of uranium complexes bearing azido- and carbon-functional groups. Alkyl, alkynyl, and azido complexes are accessed in a single step from commer

Carbon-gold bond formation through [3 + 2] cycloaddition reactions of gold(I) azides and terminal alkynes

Carbon-gold bond formation propels a growing number of homogeneous catalyses, but the C-Au bond formation itself is comparatively underinvestigated. Reported here are C-Au bond-forming reactions that result from [3 + 2] cycloaddition of (triphenylphosphine)gold(I) azide to terminal alkynes. The reaction proceeds with the preformed azide complex or, in situ, by reaction of the corresponding gold(I) alkynyl with trimethylsilyl azide in the presence of protic solvents. This metal-mediated cycloaddition is analogous to the Huisgen dipolar addition of azides and alkynes and provides access to new classes of gold-bearing compounds and materials.

Cluster synthesis by photolysis of R3PAuN3. Crystal structure of OH and NO3

Photolysis of R3PAuN3 (1) results in a reductive elimination of the azide group yielding R3PAu0 moieties which then combine to form Au clusters.In the presence of metal carbonyls heterometalic clusters are obtained.In the case of Mo(CO)6 the ca