dicarbonyldihydridobis(triphenylphosphine)osmium

Base Information

Chemical Name:dicarbonyldihydridobis(triphenylphosphine)osmium
CAS No.:18974-23-7
Molecular Formula:C₃₈H₃₂O₂OsP₂
Molecular Weight:772.818
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of dicarbonyldihydridobis(triphenylphosphine)osmium

Chemical Property:

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Technology Process of dicarbonyldihydridobis(triphenylphosphine)osmium

There total 6 articles about dicarbonyldihydridobis(triphenylphosphine)osmium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 22372-70-9
tetracarbonyldihydroosmium

: 18974-23-7,25702-68-5
dicarbonyldihydridobis(triphenylphosphine)osmium

: 99782-58-8
H₂Os(CO)3P(C₆H₅)3

Guidance literature:: With 2,2'-azobis(isobutyronitrile); triphenylphosphine; In benzene; H2Os(CO)4 was transferred in vacuo to a vacuum-line reaction bulb containing PPh3, AIBN and benzene, soln. was degassed, kept at 35°C; reaction mixt. was sampled by quenching the soln. at 0°C and removing of aliquot by syringe under a heavy flow of N2 or Ar; product was identified by its IR spectrum; Kinetics;
DOI:10.1021/ja00265a018

Reference yield:

: 25838-88-4
[OsH(CO)3(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[OsH(CO)3(P(C₆H₅)3)2]ClO₄

: 33635-55-1,20332-51-8
Os(CO)3(triphenylphosphine)2

: 18974-23-7,25702-68-5
dicarbonyldihydridobis(triphenylphosphine)osmium

Guidance literature:: Multi-step reaction with 2 steps

1: NaBH₄ / ethanol; dichloromethane

2: not given

With NaBH₄; In ethanol; dichloromethane;
DOI:10.1016/S0022-328X(00)81212-7

Reference yield:

: Os(CH₂O)(CO)2(P(C₆H₅)3)2*H₂O

: 18974-23-7,25702-68-5
dicarbonyldihydridobis(triphenylphosphine)osmium

Guidance literature:: In neat (no solvent, solid phase); Irradiation (UV/VIS); irradiated with pyrex-filtered sunlight for weeks;
DOI:10.1016/S0022-328X(00)81212-7