Os(PEt₂Ph)3Cl₃

Base Information

Chemical Name:Os(PEt₂Ph)3Cl₃
CAS No.:23677-84-1
Molecular Formula:C₃₀H₄₅Cl₃OsP₃
Molecular Weight:795.168
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Os(PEt₂Ph)3Cl₃

Chemical Property:

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Technology Process of Os(PEt₂Ph)3Cl₃

There total 9 articles about Os(PEt₂Ph)3Cl₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: 20816-12-0
osmium(VIII) oxide

: 1605-53-4
diethyl-phenyl-phosphine

: [(P(C₂H₅)2C₆H₅)3Os(Cl)3Os(P(C₂H₅)2C₆H₅)3]⁽¹⁺⁾

: 23677-84-1,25434-95-1
mer-{OsCl3(PEt2Ph)3}

Guidance literature:: In ethanol; reflux (15 min); filtration, chromy. (SiO2; CH2Cl2);

Reference yield: 55.0%

: 20816-12-0
osmium(VIII) oxide

: 1605-53-4
diethyl-phenyl-phosphine

: 23677-84-1,25434-95-1
mer-{OsCl3(PEt2Ph)3}

Guidance literature:: With HCl; In ethanol; ligand is added to nitrogen-purged soln. of OsO4 and concd. HCl in ethanol, soln. is refluxed for ca. 2 h; soln. is evapd. under reduced pressure, stored at 0°C overnight, filtn., washed (diethyl ether), dried (vac.); elem anal.;
DOI:10.1039/DT9900002609

Reference yield: 45.0%

: 20816-12-0
osmium(VIII) oxide

: 1605-53-4
diethyl-phenyl-phosphine

: 23677-84-1,25434-95-1
mer-{OsCl3(PEt2Ph)3}

: 84960-62-3
trans-OsO₂Cl₂(P(C₂H₅)2C₆H₅)2

Guidance literature:: With HCl; In ethanol; under N2, 1 equiv of OsO4 was dissolved in mixt. of abs. EtOH and 15 equiv of concd. HCl, 6 equiv of PEt2Ph was added, stirred for 6 h in absence of light; filtered, washed with EtOH, dried, recrystd. from CH2Cl2, Et2O added, filtered, washed with Et2O, dried in vac. (trans-complex), filtrate reduced in volume, refrigerated for 24 h, filtered, washed with cold EtOH, dried in vac. (mer-complex); elem. anal.;