mer-tris(carbonyl)iridium(III) fluorosulfate

Base Information

• Chemical Name: mer-tris(carbonyl)iridium(III) fluorosulfate
• CAS No.: 173790-22-2
• Molecular Formula: C₃F₃IrO₁₂S₃
• Molecular Weight: 573.439
• Mol file: 173790-22-2.mol

Synonyms:

Chemical Property of mer-tris(carbonyl)iridium(III) fluorosulfate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of mer-tris(carbonyl)iridium(III) fluorosulfate

There total 2 articles about mer-tris(carbonyl)iridium(III) fluorosulfate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

bis(fluorosulfuryl) peroxide (13709-32-5) + carbon monoxide (201230-82-2) + fluorosulphonic acid (7789-21-1) + iridium → fac-tris(carbonyl)iridium(III) fluorosulfate (173790-22-2,173936-44-2) + mer-tris(carbonyl)iridium(III) fluorosulfate (173790-22-2,173936-44-2)

Guidance literature:

In fluorosulphonic acid; repeated treatment of Ir-powder with mixt. of FSO3H and S2F6O2 (120°C, 16 h, stirring), decantation and back distn. onto remaining Ir (todissoln.), removal of volatiles, HSO3F addn., heating under 2 atm CO (6 0°C, 4 d); concn. (crystn.), recrystn. (HSO3F); elem. anal.;

DOI:10.1021/ic9506769

Reference yield: 70.0%

bis(fluorosulfuryl) peroxide (13709-32-5) + carbon monoxide (201230-82-2) + fluorosulphonic acid (7789-21-1) + iridium → fac-tris(carbonyl)iridium(III) fluorosulfate (173790-22-2,173936-44-2) + mer-tris(carbonyl)iridium(III) fluorosulfate (173790-22-2,173936-44-2)

Guidance literature:

In fluorosulphonic acid; repeated treatment of Ir-powder with mixt. of FSO3H and S2F6O2 (120°C, 16 h, stirring), decantation and back distn. onto remaining Ir (todissoln.), removal of volatiles, HSO3F addn., heating under 2 atm CO (6 0°C, 4 d); concn. (crystn.), recrystn. (HSO3F); elem. anal.;

DOI:10.1021/ic9506769

upstream raw materials:

bis(fluorosulfuryl) peroxide

carbon monoxide

fluorosulphonic acid