[Pt(CH₃)(CC(C₆H₅))(P(C₆H₅)3)2]

Base Information

• Chemical Name: [Pt(CH₃)(CC(C₆H₅))(P(C₆H₅)3)2]
• CAS No.: 161098-80-2
• Molecular Formula: C₄₅H₃₈P₂Pt
• Molecular Weight: 835.824

Synonyms:

Chemical Property of [Pt(CH₃)(CC(C₆H₅))(P(C₆H₅)3)2]

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of [Pt(CH₃)(CC(C₆H₅))(P(C₆H₅)3)2]

There total 1 articles about [Pt(CH₃)(CC(C₆H₅))(P(C₆H₅)3)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.4%

trans-chloro(methyl)bis(triphenylphosphine)platinum(II) + phenylacetylene (536-74-3) → [Pt(CH3)(CC(C6H5))(P(C6H5)3)2] (161098-80-2)

Guidance literature:

With AgBF₄; triethylamine; In acetone; byproducts: AgCl; N2; Pt-compd. suspn. and Ag.compd. soln. stirring 1 h, filtration (AgClremoval), treatment with org. compds., mixt. stirring overnight, filtration, solid treatment with CH2Cl2, soln. filtration, vol. redn., pptn. on n-pentane addn.; ppt. filtration off, vac. drying; elem. anal.;

DOI:10.1016/0020-1693(95)04584-8

Reference yield: 60.6%

tetrafluoroboric acid + [Pt(CH3)(CC(C6H5))(P(C6H5)3)2] (161098-80-2) + 1-chloro-3-hydroxypropane (627-30-5) → [Pt(CH3)(C(OCH2CH2CH2Cl)(CH2C6H4CH3))(P(C6H5)3)2](1+)*BF4(1-)=[Pt(CH3)(C(OC3H6Cl)(C8H9))(P(C6H5)3)2](BF4)

Guidance literature:

In diethyl ether; benzene; N2; mixing Pt-compd. soln. (C6H6) and B-compd. soln. (Et2O) at 0°C, org. compd. soln. (C6H6) addn., mixt. slow warming to room temp., pptn. on stirring overnight; ppt. filtration off, washing (n-pentane), vac. drying; elem. anal.;

DOI:10.1016/0020-1693(95)04584-8

Reference yield:

tetrafluoroboric acid diethyl ether (67969-82-8) + [Pt(CH3)(CC(C6H5))(P(C6H5)3)2] (161098-80-2) + water (7732-18-5) → {(PPh3)2(μ-hydroxo)platinum(II)}2(BF4)2 + trans-[Pt(Me)(CO)(PPh3)2][BF4] (33915-38-7)

Guidance literature:

In dichloromethane-d2; byproducts: p-xylene, CH3CH=CHC6H5; N2-atmosphere; addn. of 1 equiv. HBF4 to Pt-complex at -40°C, standing at -20°C, then at 0°C, addn. of water, standing for8 h at room temp. (crystn. of carbonyl complex); monitoring by (1)H- and (31)P-NMR spectroscopy; product mixt. not sepd., detd. by (31)P-NMR spectroscopy;

DOI:10.1016/S0022-328X(99)00119-9

upstream raw materials:

phenylacetylene

Downstream raw materials:

trans-[Pt(Me)(CO)(PPh₃)2][BF₄]

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