tin(II) meso-tetraphenylporphyrin

Base Information

• Chemical Name: tin(II) meso-tetraphenylporphyrin
• CAS No.: 129390-28-9
• Molecular Formula: C₄₄H₂₈N₄Sn
• Molecular Weight: 731.443
• Mol file: 129390-28-9.mol

Synonyms:

Chemical Property of tin(II) meso-tetraphenylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tin(II) meso-tetraphenylporphyrin

There total 2 articles about tin(II) meso-tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + tin(ll) chloride → tin(II) meso-tetraphenylporphyrin (129390-28-9)

Guidance literature:

With pyridine; In tetrahydrofuran; (Ar); addn. of pyridine to soln. of compounds in presence of molecular sieves; refluxed for 6 h while stirred; reaction monitored by UV-vis spectroscopy;; filtration; evapn. (reduced pressure); chromy. (toluene, alumina); solvent removed; recrystn. (toluene); purity checked by (1)H NMR, UV-vis and IR spectroscopy;

Reference yield:

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + tin(ll) chloride → tin(II) tetraphenylphorphyrin (129390-28-9)

Guidance literature:

With pyridine; In tetrahydrofuran; pyridine; reaction was carried out in Vacuum Atmospheres glove box; anhydrous SnCl2 dissolved in hot THF reacts with H2TPP in the presence of pyridine atreflux for 5-10 min; filtration after cooling; elem. anal.;

DOI:10.1016/S0020-1693(00)80734-3

Reference yield:

tin(II) meso-tetraphenylporphyrin (129390-28-9) → trans-dihydroxo(meso-tetraphenylporphyrinato)tin(IV) (26334-89-4)

Guidance literature:

With H₂O; reaction with trace moisture;

upstream raw materials:

5,10,15,20-tetraphenyl-21H,23H-porphine

Downstream raw materials:

trans-dihydroxo(meso-tetraphenylporphyrinato)tin(IV)

(TPP)SnS