2-Diazonio-1-[(3-phenylprop-2-en-1-yl)oxy]ethen-1-olate

Base Information

Chemical Name:2-Diazonio-1-[(3-phenylprop-2-en-1-yl)oxy]ethen-1-olate
CAS No.:132316-71-3
Molecular Formula:C11H10N2O2
Molecular Weight:202.213
Hs Code.:
DSSTox Substance ID:DTXSID20708314

Synonyms:132316-71-3;cinnamyl 2-diazoacetate;2-Diazonio-1-[(3-phenylprop-2-en-1-yl)oxy]ethen-1-olate;DTXSID20708314

Suppliers and Price of 2-Diazonio-1-[(3-phenylprop-2-en-1-yl)oxy]ethen-1-olate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 2-Diazonio-1-[(3-phenylprop-2-en-1-yl)oxy]ethen-1-olate

Chemical Property:

XLogP3:2.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:202.074227566
Heavy Atom Count:15
Complexity:274

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)C=CCOC(=O)C=[N+]=[N-]

Technology Process of 2-Diazonio-1-[(3-phenylprop-2-en-1-yl)oxy]ethen-1-olate

There total 7 articles about 2-Diazonio-1-[(3-phenylprop-2-en-1-yl)oxy]ethen-1-olate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 61363-91-5
(E)-(3-phenylallyl) 3-oxo-butyrate

: 132316-71-3
trans-cinnamyl α-diazoacetate

Guidance literature:: With sodium hydroxide; 4-toluenesulfonyl azide; tetrabutylammomium bromide; In dichloromethane; at 20 ℃;
DOI:10.1021/jo010728d

Reference yield: 82.0%

: 2158-14-7
4-acetamidobenzenesulfonyl azide

: 5394-63-8
2,2,6-trimethyl-4H-1,3-dioxin-4-one

: 4407-36-7
(2E)-3-phenyl-2-propen-1-ol

: 132316-71-3
trans-cinnamyl α-diazoacetate

Guidance literature:: 2,2,6-trimethyl-4H-1,3-dioxin-4-one; (2E)-3-phenyl-2-propen-1-ol; In tetrahydrofuran; Heating;

4-acetamidobenzenesulfonyl azide; In acetonitrile; at 20 ℃;

With lithium hydroxide;
DOI:10.1016/S0960-894X(02)00793-X

Reference yield:

: 4407-36-7
(2E)-3-phenyl-2-propen-1-ol

: 132316-71-3
trans-cinnamyl α-diazoacetate

Guidance literature:: Multi-step reaction with 2 steps

1: K₂CO₃ / CH₂Cl₂ / 20 °C

2: DBU; N,N'-ditosylhydrazine / tetrahydrofuran / 0 °C

With potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ol701432k