Butanoic acid, 3-oxo-, (2E)-3-phenyl-2-propenyl ester

Base Information

• Chemical Name: Butanoic acid, 3-oxo-, (2E)-3-phenyl-2-propenyl ester
• CAS No.: 61363-91-5
• Molecular Formula: C13H14O3
• Molecular Weight: 218.252
• Mol file: 61363-91-5.mol

Synonyms:Acetessigsaeure-trans-cinnamylester;cinnamyl acetoacetate;acetoacetic acid trans-cinnamyl ester;

Chemical Property of Butanoic acid, 3-oxo-, (2E)-3-phenyl-2-propenyl ester

Chemical Property:

• PSA: 43.37000
• LogP: 2.22210

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Butanoic acid, 3-oxo-, (2E)-3-phenyl-2-propenyl ester

There total 8 articles about Butanoic acid, 3-oxo-, (2E)-3-phenyl-2-propenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

ethyl acetoacetate (141-97-9) + (2E)-3-phenyl-2-propen-1-ol (4407-36-7) → (E)-(3-phenylallyl) 3-oxo-butyrate (61363-91-5)

Guidance literature:

H-Beta zeolite; In toluene; at 110 ℃; for 8h;

DOI:10.1039/CC9960000707

Reference yield: 95.0%

acetoacetic acid methyl ester (105-45-3) + (2E)-3-phenyl-2-propen-1-ol (4407-36-7) → (E)-(3-phenylallyl) 3-oxo-butyrate (61363-91-5)

Guidance literature:

With Candida antarctica lipase B immobilized on macroporous resin; at 40 ℃; for 8h; under 10 Torr;

DOI:10.1021/jo001478o

Reference yield: 89.0%

2,2,6-trimethyl-4H-1,3-dioxin-4-one (5394-63-8) + (2E)-3-phenyl-2-propen-1-ol (4407-36-7) → (E)-(3-phenylallyl) 3-oxo-butyrate (61363-91-5)

Guidance literature:

In xylene; at 150 ℃; for 0.5h;

DOI:10.1021/ja00126a016

upstream raw materials:

ethyl acetoacetate

(2E)-3-phenyl-2-propen-1-ol

4-methyleneoxetan-2-one

3-Phenylpropenol

Downstream raw materials:

4-phenyl-5-hexen-2-one

(E)-6-phenylhex-5-en-2-one

3-<3-phenyl-2(E)-propen-1-yl>-6-phenyl-5(E)-hexen-2-one

cinnamyl 2-chloroacetoacetate