Hydroperoxide, cyclopentylidenebis-

Base Information

• Chemical Name: Hydroperoxide, cyclopentylidenebis-
• CAS No.: 132606-28-1
• Molecular Formula: C5H10O4
• Molecular Weight: 134.132
• Mol file: 132606-28-1.mol

Synonyms:

Chemical Property of Hydroperoxide, cyclopentylidenebis-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Hydroperoxide, cyclopentylidenebis-

There total 1 articles about Hydroperoxide, cyclopentylidenebis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

1,1-dimethoxycyclopentane (931-94-2) → 1,1’-dihydroperoxydi(cyclopentyl)peroxide (4884-13-3) + 1,1-bis(hydroperoxy)cyclopentane (132606-28-1) + cyclopentanone (120-92-3)

Guidance literature:

With dihydrogen peroxide; ortho-tungstic acid; In acetonitrile; at 0 ℃; for 40h;

Reference yield: 79.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 1,1-bis(hydroperoxy)cyclopentane (132606-28-1) + 4-fluoroaniline (371-40-4) → 9-(4-fluorophenyl)-6,7,11,12-tetraoxa-9-azaspiro[4.7]dodecane

Guidance literature:

formaldehyd; 1,1-bis(hydroperoxy)cyclopentane; With samarium(III) nitrate hexahydrate; In tetrahydrofuran; water; at 20 ℃; for 0.25h;

4-fluoroaniline; In tetrahydrofuran; water; at 20 ℃; for 6h; chemoselective reaction;

DOI:10.1134/S1070428019050075

Reference yield: 76.0%

bis(methoxymethyl)diphenylsilane + 1,1-bis(hydroperoxy)cyclopentane (132606-28-1) → 9,9-diphenyl-6,7,11,12-tetraoxa-9-silaspiro[4.7]dodecane

Guidance literature:

With lanthanum(III) nitrate hexahydrate; In tetrahydrofuran; at 20 ℃; for 6h; Reagent/catalyst; Schlenk technique;

DOI:10.1134/S1070428020100024

upstream raw materials:

1,1-dimethoxycyclopentane

Downstream raw materials:

N-(4-chlorophenyl)piperidine

Refernces