C₁₈H₂₅ClOSi

Base Information

• Chemical Name: C₁₈H₂₅ClOSi
• CAS No.: 1432499-30-3
• Molecular Formula: C₁₈H₂₅ClOSi
• Molecular Weight: 320.934
• Mol file: 1432499-30-3.mol

Synonyms:

Chemical Property of C₁₈H₂₅ClOSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₈H₂₅ClOSi

There total 3 articles about C₁₈H₂₅ClOSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-phenylhex-5-enoic acid (156297-00-6) → C18H25ClOSi (1432499-30-3)

Guidance literature:

Multi-step reaction with 4 steps

1.1: lithium aluminium tetrahydride / tetrahydrofuran / 18 h / 0 - 20 °C / Inert atmosphere

2.1: pyridinium chlorochromate / dichloromethane / 2 h / 20 °C / Inert atmosphere

3.1: zinc; ammonium chloride / toluene; water; tetrahydrofuran / 10 h / 0 - 20 °C / Inert atmosphere

4.1: zinc dibromide; lithium diisopropyl amide / tetrahydrofuran / 1 h / -78 - -20 °C / Inert atmosphere

4.2: 2 h / -78 °C / Inert atmosphere

With lithium aluminium tetrahydride; ammonium chloride; pyridinium chlorochromate; zinc dibromide; zinc; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; water; toluene;

DOI:10.1021/ja4025963

Reference yield:

2-phenyl-5-hexen-1-ol (177037-77-3) → C18H25ClOSi (1432499-30-3)

Guidance literature:

Multi-step reaction with 3 steps

1.1: pyridinium chlorochromate / dichloromethane / 2 h / 20 °C / Inert atmosphere

2.1: zinc; ammonium chloride / toluene; water; tetrahydrofuran / 10 h / 0 - 20 °C / Inert atmosphere

3.1: zinc dibromide; lithium diisopropyl amide / tetrahydrofuran / 1 h / -78 - -20 °C / Inert atmosphere

3.2: 2 h / -78 °C / Inert atmosphere

With ammonium chloride; pyridinium chlorochromate; zinc dibromide; zinc; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; water; toluene;

DOI:10.1021/ja4025963

Reference yield:

2-phenyl-5-hexenal (53847-17-9) → C18H25ClOSi (1432499-30-3)

Guidance literature:

Multi-step reaction with 2 steps

1.1: zinc; ammonium chloride / toluene; water; tetrahydrofuran / 10 h / 0 - 20 °C / Inert atmosphere

2.1: zinc dibromide; lithium diisopropyl amide / tetrahydrofuran / 1 h / -78 - -20 °C / Inert atmosphere

2.2: 2 h / -78 °C / Inert atmosphere

With ammonium chloride; zinc dibromide; zinc; lithium diisopropyl amide; In tetrahydrofuran; water; toluene;

DOI:10.1021/ja4025963

upstream raw materials:

2-phenylhex-5-enoic acid

2-phenyl-5-hexen-1-ol

2-phenyl-5-hexenal

Downstream raw materials:

C₁₅H₁₅ClO

C₁₅H₁₇ClO