di-μ-benzoato-dicarbonyl(η5-cyclopentadienyl)((4-methylpyridine)copper)molybdenum(Cu-Mo)

Base Information

• Chemical Name: di-μ-benzoato-dicarbonyl(η5-cyclopentadienyl)((4-methylpyridine)copper)molybdenum(Cu-Mo)
• CAS No.: 108451-99-6
• Molecular Formula: C₂₇H₂₂CuMoNO₆
• Molecular Weight: 615.961
• Mol file: 108451-99-6.mol

Synonyms:

Chemical Property of di-μ-benzoato-dicarbonyl(η5-cyclopentadienyl)((4-methylpyridine)copper)molybdenum(Cu-Mo)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of di-μ-benzoato-dicarbonyl(η5-cyclopentadienyl)((4-methylpyridine)copper)molybdenum(Cu-Mo)

There total 1 articles about di-μ-benzoato-dicarbonyl(η5-cyclopentadienyl)((4-methylpyridine)copper)molybdenum(Cu-Mo) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

picoline (108-89-4) + methyl-tricarbonyl(η-cyclopentadienyl)molybdenum + Copper(I); benzoate (533-01-7,2989-37-9,3113-85-7,14067-34-6,14604-51-4,113596-35-3) + benzoic acid (65-85-0,8013-63-6) → di-μ-benzoato-dicarbonyl(η5-cyclopentadienyl)((4-methylpyridine)copper)molybdenum(Cu-Mo) (108451-99-6)

Guidance literature:

With K₂CO₃; HBF₄; In diethyl ether; dichloromethane; addn. of PhCOOH and HBF4 in ether (dropwise) to a soln. of Mo-complex in CH2Cl2 (N2, 25°C), stirring for 1 h, addn. of K2CO3, stirring (2 h), evapn., extn. (ether), addn. of PhCO2Cu and MeC5H4N, stirring (room temp., 1 h); chromy. on silica gel, elution with THF yields dark red fraction, evapn. to dryness in vac., recrystn. from benzene/pentane, elem. anal.;

upstream raw materials:

picoline

Copper(I); benzoate

benzoic acid