Zn[C₅Me₄(3,5-^tBu₂C₆H₃)]2

Base Information

Chemical Name:Zn[C₅Me₄(3,5-^tBu₂C₆H₃)]2
CAS No.:1239962-17-4
Molecular Formula:C₄₆H₆₆Zn
Molecular Weight:684.42
Hs Code.:

Zn[C<sub>5</sub>Me<sub>4</sub>(3,5-<sup>t</sup>Bu<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)]2

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Chemical Property of Zn[C₅Me₄(3,5-^tBu₂C₆H₃)]2

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Technology Process of Zn[C₅Me₄(3,5-^tBu₂C₆H₃)]2

There total 1 articles about Zn[C₅Me₄(3,5-^tBu₂C₆H₃)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: C₅H(CH₃)4C₆H₃(C(CH₃)3)2

: 7646-85-7,24359-56-6
zinc(II) chloride

: 1239962-17-4
Zn[C₅Me₄(3,5-^tBu₂C₆H₃)]2

Guidance literature:: With KH; In tetrahydrofuran; under Ar; ligand slowly added to suspn. of KH in THF; stirred at room temp. for 16 h; solvent removed under vac.; washed with pentane; dried in vac.; mixed with ZnCl2 in THF; stirred at 20°C for 6 h; solvent removed under vac.; extd. with pentane; concd.; crystd. at -23°C; elem. anal.;
DOI:10.1021/om100412q

Reference yield: 89.0%

: chlorobis(ethylene)rhodium(I) dimer

: 1239962-17-4
Zn[C₅Me₄(3,5-^tBu₂C₆H₃)]2

: 513-81-5
2,3-dimethyl-buta-1,3-diene

: 1239962-27-6
(η5-(t-Bu2C6H3)-tetramethylcyclopentadienyl)Rh(η4-CH2=CMeCMe=CH2)

Guidance literature:: In tetrahydrofuran; byproducts: ZnCl2; under Ar; CH2C(Me)C(Me)CH2 added at 0°C to soln. of Rh complex inTHF; stirred at 0°C for 15 min and at room temp. for 1.5 h; soln . of Zn complex in THF added; stirred for 12 h; solvent removed under vac.; extd. with pentane; solvent removed; elem. anal.;
DOI:10.1021/om100412q

Reference yield: 80.0%

: chlorobis(ethylene)rhodium(I) dimer

: 1239962-17-4
Zn[C₅Me₄(3,5-^tBu₂C₆H₃)]2

: 1239962-21-0
(η5-(3,5-t-Bu2C6H3)-tetramethylcyclopentadienyl)Rh(C2H4)2

Guidance literature:: In tetrahydrofuran; byproducts: ZnCl2; under Ar; soln. of Zn complex in THF added at 0°C to soln. of Rh complex in THF; stirred for 12 h; solvent removed under vac.; extd. with pentane; solvent removed; elem. anal.;
DOI:10.1021/om100412q