[(η(5)-C5Me5)(CO)2FeAsC(Ph)NMe2]

Base Information

Chemical Name:[(η(5)-C5Me5)(CO)2FeAsC(Ph)NMe2]
CAS No.:352201-43-5
Molecular Formula:C₂₁H₂₆AsFeNO₂
Molecular Weight:455.212
Hs Code.:

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Chemical Property of [(η(5)-C5Me5)(CO)2FeAsC(Ph)NMe2]

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Technology Process of [(η(5)-C5Me5)(CO)2FeAsC(Ph)NMe2]

There total 1 articles about [(η(5)-C5Me5)(CO)2FeAsC(Ph)NMe2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: [Fe(pentamethylcyclopentadienyl)(CO)₂Cl]

: 1.5C₄H₈O*C₆H₁₈AsSi₂^(1-)*Li⁽¹⁺⁾

: 6485-11-6
dimethyl-(methylsulfanyl-phenyl-methylene)-ammonium; iodide

: 432004-57-4,352201-43-5
[(η(5)-C5Me5)(CO)2FeAsC(Ph)NMe2]

Guidance literature:: In 1,2-dimethoxyethane; pentane; byproducts: LiI, MeSSiMe3, Me3SiCl; all manipulations under N2; soln. of Li compd. in DME added dropwise to suspn. of carbenium salt in pentane/DME at -78°C in 1 h, warmed to -20°C, filtered, filtrate dild. with pentane, Fe complex added,stirred for 16 h at room temp.; soln. concd., filtered, washed with Et2O, solvents evapd. from filtrate,dried for 16 h at 1E-3 mbar, residue dissolved in Et2O, filtered over s iccated Na2SO4, allowed to stand for 48 h at -28°C; elem. anal.;
DOI:10.1002/1521-3749(200105)627:5<863::AID-ZAAC863>3.0.CO;2-J

Reference yield: 92.0%

: tetrafluoroboric acid

: 432004-57-4,352201-43-5
[(η(5)-C5Me5)(CO)2FeAsC(Ph)NMe2]

: 352201-46-8
[(η(5)-C5Me5)(CO)2FeAs(H)C(Ph)NMe2]BF4

Guidance literature:: In diethyl ether; all manipulations under N2; soln. of HBF4 added to cooled soln. of complex at -40°C, after 1 h warmed to room temp.; filtered, washed with Et2O, dried; elem. anal.;
DOI:10.1002/1521-3749(200105)627:5<863::AID-ZAAC863>3.0.CO;2-J

Reference yield: 86.0%

: 432004-57-4,352201-43-5
[(η(5)-C5Me5)(CO)2FeAsC(Ph)NMe2]

: 333-27-7
methyl trifluoromethanesulfonate

: 352201-49-1
[(η(5)-C5Me5)(CO)2FeAs(Me)C(Ph)NMe2]SO3CF3

Guidance literature:: In diethyl ether; all manipulations under N2; soln. of CF3SO3Me added dropwise to cooled soln. of complex at -40°C; filtered, washed with Et2O, dried; elem. anal.;
DOI:10.1002/1521-3749(200105)627:5<863::AID-ZAAC863>3.0.CO;2-J