trans-[bis(N,N,N',N'-tetramethylethane-1,2-diamine)FeCl₂]*((CH₃)2C₃H₂NOC₆H₄S)2

Base Information

Chemical Name:trans-[bis(N,N,N',N'-tetramethylethane-1,2-diamine)FeCl₂]*((CH₃)2C₃H₂NOC₆H₄S)2
CAS No.:1237706-77-2
Molecular Formula:C₁₂H₃₂Cl₂FeN₄*C₂₂H₂₄N₂O₂S₂
Molecular Weight:771.743
Hs Code.:

trans-[bis(N,N,N',N'-tetramethylethane-1,2-diamine)FeCl<sub>2</sub>]*((CH<sub>3</sub>)2C<sub>3</sub>H<sub>2</sub>NOC<sub>6</sub>H<sub>4</sub>S)2

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Chemical Property of trans-[bis(N,N,N',N'-tetramethylethane-1,2-diamine)FeCl₂]*((CH₃)2C₃H₂NOC₆H₄S)2

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Technology Process of trans-[bis(N,N,N',N'-tetramethylethane-1,2-diamine)FeCl₂]*((CH₃)2C₃H₂NOC₆H₄S)2

There total 2 articles about trans-[bis(N,N,N',N'-tetramethylethane-1,2-diamine)FeCl₂]*((CH₃)2C₃H₂NOC₆H₄S)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.5%

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: 240123-81-3
2-(4',4'-dimethyloxazolin-2'-yl)thiophenolato lithium

: 7705-08-0
iron(III) chloride

: 112440-08-1
{Fe(TMEDA)Cl₂}₂

: 1237706-77-2
trans-[bis(N,N,N',N'-tetramethylethane-1,2-diamine)FeCl₂]*((CH₃)2C₃H₂NOC₆H₄S)2

Guidance literature:: In tetrahydrofuran; Li salt of ligand in THF slowly added to a stirred soln. of 1 equiv. of FeCl3 in THF, stirred at room temp. for 2 h, treated with tmen (2 equiv.) dropwisw, stirred at room temp. for 16 h; dried (vac.), cooled to -20°C for 3 weeks, filtered, filtrate evapd. (cooled to -20°C), mother liquor layered with hexane, crystd., filtered, dried (vac.), elem. anal.;
DOI:10.1002/ejic.201000065

Reference yield: 46.0%

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: 240123-81-3
2-(4',4'-dimethyloxazolin-2'-yl)thiophenolato lithium

: 7705-08-0
iron(III) chloride

: 1237706-74-9
bis(2-(4,4'-dimethyloxazolin-2'-yl)thiophenolato)iron(II)

: 1237706-77-2
trans-[bis(N,N,N',N'-tetramethylethane-1,2-diamine)FeCl₂]*((CH₃)2C₃H₂NOC₆H₄S)2

Guidance literature:: In tetrahydrofuran; Li salt of ligand in THF slowly added to a stirred soln. of 0.5 equiv. of FeCl3 in THF, stirred at room temp. for 2 h, treated with tmen (2 equiv.) dropwisw, stirred at room temp. for 2 d; evapd.(vac.), layered with hexane, cooled to -20°C (repeated several times);
DOI:10.1002/ejic.201000065