trans-iodo(N-methylbenzamide-C⁽³⁾)bis(triphenylphosphine)platinum(II)

Base Information

• Chemical Name: trans-iodo(N-methylbenzamide-C⁽³⁾)bis(triphenylphosphine)platinum(II)
• CAS No.: 694528-54-6
• Molecular Formula: C₄₄H₃₈INOP₂Pt
• Molecular Weight: 980.724
• Mol file: 694528-54-6.mol

Synonyms:

Chemical Property of trans-iodo(N-methylbenzamide-C⁽³⁾)bis(triphenylphosphine)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of trans-iodo(N-methylbenzamide-C⁽³⁾)bis(triphenylphosphine)platinum(II)

There total 1 articles about trans-iodo(N-methylbenzamide-C⁽³⁾)bis(triphenylphosphine)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

tetrakis(triphenylphosphine)platinum (14221-02-4) + 3-iodo-N-methylbenzamide (90434-01-8) → trans-iodo(N-methylbenzamide-C(3))bis(triphenylphosphine)platinum(II) (694528-54-6)

Guidance literature:

In toluene; under N2; soln. of 3-iodo-N-methylbenzamide and Pt(PPh3)4 in toluene stirred at 80°C for 16 h; hexane added, ppt. sepd. by filtration; elem. anal.;

DOI:10.1139/V08-116

Reference yield: 81.0%

4,4′-methylene-bispyrazole (13753-57-6) + trans-iodo(N-methylbenzamide-C(3))bis(triphenylphosphine)platinum(II) (694528-54-6) + silver trifluoromethanesulfonate (2923-28-6) → trans-μ-4,4'-dipyrazolylmethane-bis[(N-methylbenzamide-C(3))bis(triphenylphosphine)platinum(II)] bis(triflate)

Guidance literature:

In dichloromethane; byproducts: AgI; under N2; Pt complex treated with AgOTf in CH2Cl2, mixt. stirred at roomtemp. in the absence of light for 3 h, soln. filtered through Celite, 4 ,4'-dipyrazolylmethane added to filtrate, mixt. stirred overnight at room temp.; evapn. under vac.; elem. anal.;

DOI:10.1139/V08-116

Reference yield: 76.0%

4,7-phenanthroline (230-07-9) + trans-iodo(N-methylbenzamide-C(3))bis(triphenylphosphine)platinum(II) (694528-54-6) + silver trifluoromethanesulfonate (2923-28-6) → trans-4,7-phenanthroline(N-mehtylbenzamide-C(3))bis(triphenylphosphine)platinum(II) triflate (694528-61-5)

Guidance literature:

In dichloromethane; acetone; byproducts: AgI; under N2; soln. of AgOTf in distd. acetone added to stirred soln. of Pt complex in CH2Cl2; stirred in the absence of light (room temp., 16 h); filtered (Celite); filtrate reduced in vac.; resultant solid and ligand dissolved in CH2Cl2; stirred for 48 h; solvent removed in vac.; recrystd. from CH2Cl2-n-hexane; elem. anal.;

DOI:10.1016/j.jorganchem.2004.01.027

upstream raw materials:

tetrakis(triphenylphosphine)platinum

3-iodo-N-methylbenzamide

Downstream raw materials:

trans-4,7-phenanthroline(N-mehtylbenzamide-C⁽³⁾)bis(triphenylphosphine)platinum(II) triflate