Rh(4,4'-di-tert-butyl-2,2'-bipyridyl)(κ2-C,C'-CH2CMe2C6H4)(CH2CMe2Ph)

Base Information

Chemical Name:Rh(4,4'-di-tert-butyl-2,2'-bipyridyl)(κ2-C,C'-CH2CMe2C6H4)(CH2CMe2Ph)
CAS No.:960377-60-0
Molecular Formula:C₃₈H₄₉N₂Rh
Molecular Weight:636.726
Hs Code.:

Synonyms:

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Chemical Property of Rh(4,4'-di-tert-butyl-2,2'-bipyridyl)(κ2-C,C'-CH2CMe2C6H4)(CH2CMe2Ph)

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Technology Process of Rh(4,4'-di-tert-butyl-2,2'-bipyridyl)(κ2-C,C'-CH2CMe2C6H4)(CH2CMe2Ph)

There total 2 articles about Rh(4,4'-di-tert-butyl-2,2'-bipyridyl)(κ2-C,C'-CH2CMe2C6H4)(CH2CMe2Ph) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: [Rh(4,4'-di-tert-butyl-2,2'-bipyridyl)Cl₃(N,N-dimethylformamide)]*0.5Et₂O

: 35293-35-7
2-methyl-2-phenyl-1-propylmagnesium chloride

: 960377-60-0
Rh(4,4'-di-tert-butyl-2,2'-bipyridyl)(κ2-C,C'-CH2CMe2C6H4)(CH2CMe2Ph)

Guidance literature:: In tetrahydrofuran; byproducts: (C6H5)C(CH3)3; (N2); using Schlenk techniques; addn. of soln. of PhMe2CCH2MgCl in THF to suspn. of Rh(4,4'-di-tert-butyl-2,2'-bipyridyl)Cl3(DMF) in THF at -78°C; stirring at this temp. for 1 h; warming to room temp.; stirring overnight; removal of volatiles in vac., extn. with hexane; concn. of extracts; cooling at -40°C; crystn., elem. anal.;
DOI:10.1021/om7006216

Reference yield:

: 72914-19-3
4,4'-di-tert-butyl-2,2'-bipyridine

: 960377-60-0
Rh(4,4'-di-tert-butyl-2,2'-bipyridyl)(κ2-C,C'-CH2CMe2C6H4)(CH2CMe2Ph)

Guidance literature:: Multi-step reaction with 2 steps

1: N,N-dimethyl-formamide

2: tetrahydrofuran

In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/om7006216

Reference yield: 86.0%

: 960377-60-0
Rh(4,4'-di-tert-butyl-2,2'-bipyridyl)(κ2-C,C'-CH2CMe2C6H4)(CH2CMe2Ph)

: 201230-82-2
carbon monoxide

: 7732-18-5
water

: [Rh(4,4'-di-tert-butyl-2,2'-bipyridyl)(CH₂CMe₂C₆H₄)(CH₂CMe₂Ph)(CO)]*0.5H₂O

Guidance literature:: In dichloromethane; (N2); using Schlenk techniques; bubbling of CO into soln. of Rh(4,4'-di-tert-butyl-2,2'-bipyridyl)(CH2CMe2C6H4)(CH2CMe2Ph) in CH2Cl2 at 0°C for 30 s; warming at room temp.; stirring for 4 h; removal of volatiles in vac., recrystn. from hexane at -40°C; elem. anal.;
DOI:10.1021/om7006216