N(P(C₆H₅)3)2⁽¹⁺⁾*W(CO)5OC(O)OH^(1-)=[N(P(C₆H₅)3)2][W(CO)5OC(O)OH]

Base Information

• Chemical Name: N(P(C₆H₅)3)2⁽¹⁺⁾*W(CO)5OC(O)OH^(1-)=[N(P(C₆H₅)3)2][W(CO)5OC(O)OH]
• CAS No.: 150697-17-9
• Molecular Formula: C₆HO₈W*C₃₆H₃₀NP₂
• Molecular Weight: 923.508
• Mol file: 150697-17-9.mol

Synonyms:

Chemical Property of N(P(C₆H₅)3)2⁽¹⁺⁾*W(CO)5OC(O)OH^(1-)=[N(P(C₆H₅)3)2][W(CO)5OC(O)OH]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N(P(C₆H₅)3)2⁽¹⁺⁾*W(CO)5OC(O)OH^(1-)=[N(P(C₆H₅)3)2][W(CO)5OC(O)OH]

There total 1 articles about N(P(C₆H₅)3)2⁽¹⁺⁾*W(CO)5OC(O)OH^(1-)=[N(P(C₆H₅)3)2][W(CO)5OC(O)OH] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

tungsten hexacarbonyl (14040-11-0) + bis(triphenylphosphine)iminium bicarbonate (144666-88-6) + carbon dioxide (124-38-9,18923-20-1) → N(P(C6H5)3)2(1+)*W(CO)5OC(O)OH(1-)=[N(P(C6H5)3)2][W(CO)5OC(O)OH] (150697-17-9)

Guidance literature:

With acetone; In acetone; Irradiation (UV/VIS); absence of air and moisture; photolyzing W(CO)6 for 2 h, addn. to PPN-salt under CO2, gentle warming, stirring for 1 h; treatment with Et2O and hexane (sepn. of oil), solidification on washingwith Et2O; elem. anal.;

DOI:10.1021/ic9516525

Reference yield: 63.0%

carbon disulfide (75-15-0,12122-00-8) + N(P(C6H5)3)2(1+)*W(CO)5OC(O)OH(1-)=[N(P(C6H5)3)2][W(CO)5OC(O)OH] (150697-17-9) → N(P(C6H5)3)2(1+)*W*5CO*SC(S)OH(1-)=[N(P(C6H5)3)2][W(CO)5SC(S)OH]

Guidance literature:

In acetone; absence of air and moisture; excess CS2, stirring for 30 min; pptn. on addn. of Et2O and hexane, washing (Et2O), drying (vac.); elem. anal.;

DOI:10.1021/ic9516525

upstream raw materials:

tungsten hexacarbonyl

bis(triphenylphosphine)iminium bicarbonate

carbon dioxide