(7aS,7'aS,E)-2,2'-bis(2,6-diisopropylphenyl)-1,1',2,2',5,5',6,6',7,7',7a,7'a-dodecahydro-3,3'-bipyrrolo[1,2-c]imidazolylidene

Base Information

Chemical Name:(7aS,7'aS,E)-2,2'-bis(2,6-diisopropylphenyl)-1,1',2,2',5,5',6,6',7,7',7a,7'a-dodecahydro-3,3'-bipyrrolo[1,2-c]imidazolylidene
CAS No.:1621189-47-6
Molecular Formula:C₃₆H₅₂N₄
Molecular Weight:540.836
Hs Code.:

Synonyms:

Suppliers and Price of (7aS,7'aS,E)-2,2'-bis(2,6-diisopropylphenyl)-1,1',2,2',5,5',6,6',7,7',7a,7'a-dodecahydro-3,3'-bipyrrolo[1,2-c]imidazolylidene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (7aS,7'aS,E)-2,2'-bis(2,6-diisopropylphenyl)-1,1',2,2',5,5',6,6',7,7',7a,7'a-dodecahydro-3,3'-bipyrrolo[1,2-c]imidazolylidene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (7aS,7'aS,E)-2,2'-bis(2,6-diisopropylphenyl)-1,1',2,2',5,5',6,6',7,7',7a,7'a-dodecahydro-3,3'-bipyrrolo[1,2-c]imidazolylidene

There total 5 articles about (7aS,7'aS,E)-2,2'-bis(2,6-diisopropylphenyl)-1,1',2,2',5,5',6,6',7,7',7a,7'a-dodecahydro-3,3'-bipyrrolo[1,2-c]imidazolylidene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1148-11-4
N-Benzyloxycarbonyl-L-proline

: 1621189-47-6
(7aS,7'aS,E)-2,2'-bis(2,6-diisopropylphenyl)-1,1',2,2',5,5',6,6',7,7',7a,7'a-dodecahydro-3,3'-bipyrrolo[1,2-c]imidazolylidene

Guidance literature:: Multi-step reaction with 5 steps

1: 4-methyl-morpholine; chloroformic acid ethyl ester / ethyl acetate / 15 h / 0 - 20 °C / Inert atmosphere; Schlenk technique

2: 5%-palladium/activated carbon; hydrogen / methanol / 15 h / 20 °C / Inert atmosphere; Schlenk technique

3: lithium aluminium tetrahydride / tetrahydrofuran / 15 h / Reflux; Inert atmosphere; Schlenk technique

4: ammonium hexafluorophosphate / 0.08 h / 145 °C / Microwave irradiation; Inert atmosphere; Schlenk technique

5: potassium tert-butylate / tetrahydrofuran / 0.75 h / 20 °C / Schlenk technique; Glovebox; Inert atmosphere

With 4-methyl-morpholine; ammonium hexafluorophosphate; lithium aluminium tetrahydride; 5%-palladium/activated carbon; potassium tert-butylate; hydrogen; chloroformic acid ethyl ester; In tetrahydrofuran; methanol; ethyl acetate;
DOI:10.1055/s-0033-1340215

Reference yield:

: C₂₅H₃₂N₂O₃

: 1621189-47-6
(7aS,7'aS,E)-2,2'-bis(2,6-diisopropylphenyl)-1,1',2,2',5,5',6,6',7,7',7a,7'a-dodecahydro-3,3'-bipyrrolo[1,2-c]imidazolylidene

Guidance literature:: Multi-step reaction with 4 steps

1: 5%-palladium/activated carbon; hydrogen / methanol / 15 h / 20 °C / Inert atmosphere; Schlenk technique

2: lithium aluminium tetrahydride / tetrahydrofuran / 15 h / Reflux; Inert atmosphere; Schlenk technique

3: ammonium hexafluorophosphate / 0.08 h / 145 °C / Microwave irradiation; Inert atmosphere; Schlenk technique

4: potassium tert-butylate / tetrahydrofuran / 0.75 h / 20 °C / Schlenk technique; Glovebox; Inert atmosphere

With ammonium hexafluorophosphate; lithium aluminium tetrahydride; 5%-palladium/activated carbon; potassium tert-butylate; hydrogen; In tetrahydrofuran; methanol;
DOI:10.1055/s-0033-1340215

Reference yield:

: 943784-90-5
(S)-N-(2,6-diisopropyl-phenyl)pyrrolidine-2-carboxamide

: 1621189-47-6
(7aS,7'aS,E)-2,2'-bis(2,6-diisopropylphenyl)-1,1',2,2',5,5',6,6',7,7',7a,7'a-dodecahydro-3,3'-bipyrrolo[1,2-c]imidazolylidene

Guidance literature:: Multi-step reaction with 3 steps

1: lithium aluminium tetrahydride / tetrahydrofuran / 15 h / Reflux; Inert atmosphere; Schlenk technique

2: ammonium hexafluorophosphate / 0.08 h / 145 °C / Microwave irradiation; Inert atmosphere; Schlenk technique

3: potassium tert-butylate / tetrahydrofuran / 0.75 h / 20 °C / Schlenk technique; Glovebox; Inert atmosphere

With ammonium hexafluorophosphate; lithium aluminium tetrahydride; potassium tert-butylate; In tetrahydrofuran;
DOI:10.1055/s-0033-1340215