C₃₇H₄₁⁽²⁾HO₆

Base Information

• Chemical Name: C₃₇H₄₁⁽²⁾HO₆
• CAS No.: 139195-43-0
• Molecular Formula: C₃₇H₄₂O₆
• Molecular Weight: 583.729
• Mol file: 139195-43-0.mol

Synonyms:

Chemical Property of C₃₇H₄₁⁽²⁾HO₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₇H₄₁⁽²⁾HO₆

There total 8 articles about C₃₇H₄₁⁽²⁾HO₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C78H82(2)H2O10Si (139195-41-8) → C37H41(2)HO6 (139195-43-0,139242-11-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 92 percent / NaOMe / methanol / Ambient temperature

With sodium methylate; In methanol;

DOI:10.1021/jo00022a039

Reference yield:

(1R,2R)-1-(2,3,4,6-O-tetrabenzyl-α-D-glucopyranosyl)-1-deuteriopropane-2,3-diol (136089-04-8) → C37H41(2)HO6 (139195-43-0,139242-11-8)

Guidance literature:

Multi-step reaction with 3 steps

1: DMAP / CH₂Cl₂ / 0.5 h / 0 °C

2: trimethyl phosphite / 24 h / 100 °C

3: 1.) BH₃*THF, 2.) 10percent aq. NaOH, 30percent H₂O₂ / 1.) THF, room temperature, overnight, 2.) room temperature

With dmap; sodium hydroxide; borane-THF; dihydrogen peroxide; phosphorous acid trimethyl ester; In dichloromethane;

DOI:10.1021/jo00022a039

Reference yield:

(1S,2S)-1-(2,3,4,6-O-tetrabenzyl-α-D-glucopyranosyl)-1-deuteriopropane-2,3-diol (136172-71-9) → C37H41(2)HO6 (139195-43-0,139242-11-8)

Guidance literature:

Multi-step reaction with 3 steps

1: DMAP / CH₂Cl₂ / 0.5 h / 0 °C

2: trimethyl phosphite / 24 h / 100 °C

3: 1.) BH₃*THF, 2.) 10percent aq. NaOH, 30percent H₂O₂ / 1.) THF, room temperature, overnight, 2.) room temperature

With dmap; sodium hydroxide; borane-THF; dihydrogen peroxide; phosphorous acid trimethyl ester; In dichloromethane;

DOI:10.1021/jo00022a039

upstream raw materials:

C₇₁H₇₅⁽²⁾HO₉Si

1-(2,3,4,6-O-tetrabenzyl-α-D-glucopyranosyl)-1(R)-deuterio-2-propene

C₇₈H₈₂⁽²⁾H₂O₁₀Si

(1R,2R)-1-(2,3,4,6-O-tetrabenzyl-α-D-glucopyranosyl)-1-deuteriopropane-2,3-diol