Pt(COMe)Cl(2-(ddiphenylphosphino)triethylamine-κ2N,P)

Base Information

Chemical Name:Pt(COMe)Cl(2-(ddiphenylphosphino)triethylamine-κ2N,P)
CAS No.:618384-79-5
Molecular Formula:C₂₀H₂₇ClNOPPt
Molecular Weight:558.947
Hs Code.:

Synonyms:

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Chemical Property of Pt(COMe)Cl(2-(ddiphenylphosphino)triethylamine-κ2N,P)

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Technology Process of Pt(COMe)Cl(2-(ddiphenylphosphino)triethylamine-κ2N,P)

There total 2 articles about Pt(COMe)Cl(2-(ddiphenylphosphino)triethylamine-κ2N,P) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 618384-75-1
PtMeCl(2-(ddiphenylphosphino)triethylamine-κ2N,P)

: 201230-82-2
carbon monoxide

: 618384-79-5
Pt(COMe)Cl(2-(ddiphenylphosphino)triethylamine-κ2N,P)

Guidance literature:: In dichloromethane; under inert atm. Pt complex was dissolved in CH2Cl2, soln. was evacd., CO (0.1 MPa) was introduced and stirred for 5 days; react. mixt. was treated with charcoal and filtered, soln. was concd. under reduced pressure, residue was recrystd. from CH2Cl2/hexane; elem. anal.;
DOI:10.1021/om030477u

Reference yield:

: 2359-97-9
2-(diphenylphosphino)triethylamine

: 618384-79-5
Pt(COMe)Cl(2-(ddiphenylphosphino)triethylamine-κ2N,P)

Guidance literature:: Multi-step reaction with 2 steps

1: benzene

2: dichloromethane

In dichloromethane; benzene;
DOI:10.1021/om030477u

Reference yield: 27.0%

: 12107-35-6
Na[CpMo(CO)3]

: 618384-79-5
Pt(COMe)Cl(2-(ddiphenylphosphino)triethylamine-κ2N,P)

: silver nitrate

: (2-(diphenylphosphino)triethylamine-κ(2)N.P)(MeCO)Pt-MoCp(CO)3

: silver(I) chloride

Guidance literature:: With AgNO₃; In tetrahydrofuran; byproducts: AgCl; under inert atm. Pt complex and AgNO3 were dissolved in THF and stirred overnight at room temp., ppt. was filtered off, filtrate was added to THF soln. Na(MoCp(CO)3) at -70°C, react. mixt. was stirred for 3 h at -30°C; volatiles were evapd., residue was extd. with toluene at -20°C, soln. was filtered and concd. under reduced pressure at -20°C, hexane was added, ppt. was filtered, washed with hexane, and dried under vac. at room temp.; elem. anal.;
DOI:10.1021/om030477u