[(η5-C5H5)2Ti(μ-H)2B(C6F5)2]

Base Information

Chemical Name:[(η5-C5H5)2Ti(μ-H)2B(C6F5)2]
CAS No.:273200-60-5
Molecular Formula:C₂₂H₁₂BF₁₀Ti
Molecular Weight:525.012
Hs Code.:

Synonyms:

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Chemical Property of [(η5-C5H5)2Ti(μ-H)2B(C6F5)2]

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Technology Process of [(η5-C5H5)2Ti(μ-H)2B(C6F5)2]

There total 5 articles about [(η5-C5H5)2Ti(μ-H)2B(C6F5)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1271-66-5
dimethyltitanocene

: 165612-94-2
bis(pentafluorophenyl)borohydride

: 273200-60-5
[(η5-C5H5)2Ti(μ-H)2B(C6F5)2]

: 170151-48-1
methylbis(pentafluorophenyl)borane

Guidance literature:: In toluene; byproducts: CH4; in air Ti-compd. was placed into a flask, flask was evacuated, toluene was condensed onto solid at -78 °C, B-compd. was dissolved in hottoluene and added to Ti-compd., soln. was warmed up to room temp., stirred overnight; solvent was removed in vac., hexanes were condensed onto residue, mixt.was filtered, ppt. was twice washed with hexanes, elem. anal.;
DOI:10.1021/om0001319

Reference yield: 86.0%

: (π-C5H5)2Ti(CH2C6H5)2

: 165612-94-2
bis(pentafluorophenyl)borohydride

: 273200-60-5
[(η5-C5H5)2Ti(μ-H)2B(C6F5)2]

: 199607-95-9
(pentafluorophenyl)2B(benzyl)

Guidance literature:: In toluene; byproducts: toluene; toluene soln. of Ti-compd. was added to toluene soln. of B-compd. at -78 °C, mixt. was warmed up to room temp., 16 h; solvent was removed in vac., hexanes was condensed onto residue, suspn.was filtered, ppt. was twice washed with hexanes;
DOI:10.1021/om0001319

Reference yield: 68.1%

: 352353-65-2
[(η5-C5H5)2Ti(μ-H)2BC8H14]

: 1109-15-5
tris(pentafluorophenyl)borate

: 273200-60-5
[(η5-C5H5)2Ti(μ-H)2B(C6F5)2]

: 9-C₆F₅-9-borabicyclo[3.3.1]nonane

Guidance literature:: In toluene; under N2; toluene was condensed into the flask charged with Ti complex and B(C6F5)3 at -78°C, warmed to room temp., stirred for 2 h; the solvent was removed under vac., the solid was washed with toluene/hexane (1/1), solid dried under vac. for 2 h;
DOI:10.1021/om010267m