(2E)-(3,3-dimethylcyclohexylidene)ethanal

Base Information

• Chemical Name: (2E)-(3,3-dimethylcyclohexylidene)ethanal
• CAS No.: 36872-03-4
• Molecular Formula: C₁₀H₁₆O
• Molecular Weight: 152.236
• Mol file: 36872-03-4.mol

Synonyms:

Chemical Property of (2E)-(3,3-dimethylcyclohexylidene)ethanal

Chemical Property:

• Vapor Pressure: 0.081mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2E)-(3,3-dimethylcyclohexylidene)ethanal

There total 54 articles about (2E)-(3,3-dimethylcyclohexylidene)ethanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(E)-N-methoxy-N-methyl-2-(3,3-dimethylcyclohexylidene)acetamide → (E)-3,3-Dimethylcyclohexane-Δ1,?-acetaldehyde (26532-25-2,36872-03-4)

Guidance literature:

With diisobutylaluminium hydride; In tetrahydrofuran; toluene; at -78 ℃; for 1h;

DOI:10.1002/1099-0690(200007)2000:13<2417::AID-EJOC2417>3.0.CO;2-X

Reference yield: 85.0%

(E)-2-(3,3-Dimethylcyclohexylidene)ethanol (30346-27-1,41370-29-0) → Boll Weevil pheromone (41370-30-3,36872-03-4)

Guidance literature:

With manganese(IV) oxide; In hexane; at 0 ℃; for 0.5h;

DOI:10.1016/S0040-4039(00)87138-5

Reference yield: 68.0%

(E)-2-(3,3-Dimethylcyclohexylidene)ethanol (30346-27-1,41370-29-0) → (E)-3,3-Dimethylcyclohexane-Δ1,?-acetaldehyde (26532-25-2,36872-03-4)

Guidance literature:

With manganese(IV) oxide; In pentane; at 0 ℃; for 0.5h;

upstream raw materials:

2,4,4,6-tetramethyl-5,6-dihydro-4H-1,3-oxazine

3,3-dimethylcyclohexanone

(E)-2-(3,3-Dimethylcyclohexylidene)ethanol

(5-methyl-3-methyleneoct-6-en-1-yl)(phenyl)sulfane

Refernces

• 1、 Mori, Kenji,Itou, Masamichi. "Pheromone Synthesis, CXV. - Synthesis of (Z)-2-Ochtoden-1-ol, (E)-2-Ochtoden-1-al, and (Z)-2-Ochtoden-1-al, the Pheromone Components of the Boll Weevil (Anthonomus grandis)". . p. 969 - 974. Retrieved 2007/10/02.
• 2、 Masaki,Hashimoto,Sakuma,Kaji. "SYNTHETIC STUDIES ON THE OCHTODANE TYPE TERPENES I. STEREOSELECTIVE CONSTRUCTION OF THE OCHTODANE SKELETON FROM MYRCENE.". . p. 3466 - 3475. Retrieved 2007/10/02.