Tetrahedron Letters p. 1481 - 1484 (1982)
Update date:2022-08-02
Topics:
Masaki, Yukio
Hashimoto, Kinji
Sakuma, Kazuhiko
Kaji, Kenji
The ochtodane skeleton is formed stereoselectively from myrcene via acid-catalyzed cyclization of the benzenesulfenyl chloride adduct and the epoxide in a biogenetic type fashion.Its application to the syntheses of two ochtodane-type monoterpenes, an aldehyde component of the boll weevil pheromone and a diol found in the red alga Ochtodes crockeri, is reported.
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(1946)
